Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst

[Image: see text] A new enantioselective peroxidation of α,β-unsaturated nitroalkenes was realized with an easily accessible acid–base bifunctional organic catalyst derived from cinchona alkaloids. This reaction provides unprecedented easy access to optically active chiral peroxides, as illustrated...

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Detalles Bibliográficos
Autores principales: Lu, Xiaojie, Deng, Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4018155/
https://www.ncbi.nlm.nih.gov/pubmed/24730647
http://dx.doi.org/10.1021/ol500677v
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author Lu, Xiaojie
Deng, Li
author_facet Lu, Xiaojie
Deng, Li
author_sort Lu, Xiaojie
collection PubMed
description [Image: see text] A new enantioselective peroxidation of α,β-unsaturated nitroalkenes was realized with an easily accessible acid–base bifunctional organic catalyst derived from cinchona alkaloids. This reaction provides unprecedented easy access to optically active chiral peroxides, as illustrated by the asymmetric synthesis of β-peroxy nitro compounds.
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spelling pubmed-40181552015-04-14 Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst Lu, Xiaojie Deng, Li Org Lett [Image: see text] A new enantioselective peroxidation of α,β-unsaturated nitroalkenes was realized with an easily accessible acid–base bifunctional organic catalyst derived from cinchona alkaloids. This reaction provides unprecedented easy access to optically active chiral peroxides, as illustrated by the asymmetric synthesis of β-peroxy nitro compounds. American Chemical Society 2014-04-14 2014-05-02 /pmc/articles/PMC4018155/ /pubmed/24730647 http://dx.doi.org/10.1021/ol500677v Text en Copyright © 2014 American Chemical Society
spellingShingle Lu, Xiaojie
Deng, Li
Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title_full Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title_fullStr Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title_full_unstemmed Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title_short Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
title_sort catalytic asymmetric peroxidation of α,β-unsaturated nitroalkenes by a bifunctional organic catalyst
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4018155/
https://www.ncbi.nlm.nih.gov/pubmed/24730647
http://dx.doi.org/10.1021/ol500677v
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AT dengli catalyticasymmetricperoxidationofabunsaturatednitroalkenesbyabifunctionalorganiccatalyst

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