Cargando…

An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)

In the title complex, [PtCl(2)(C(12)H(6)N(2)O(2))]·CH(3)CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N(2)Cl(2) donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally di...

Descripción completa

Detalles Bibliográficos
Autores principales: Hamala, Amanda, Fritz, Carissa, Rawji, Gulnar, Lynch, Vincent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029211/
https://www.ncbi.nlm.nih.gov/pubmed/24855465
http://dx.doi.org/10.1107/S160053681303256X
Descripción
Sumario:In the title complex, [PtCl(2)(C(12)H(6)N(2)O(2))]·CH(3)CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N(2)Cl(2) donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any π–π inter­actions between aromatic rings.