An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)

In the title complex, [PtCl(2)(C(12)H(6)N(2)O(2))]·CH(3)CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N(2)Cl(2) donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally di...

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Detalles Bibliográficos
Autores principales: Hamala, Amanda, Fritz, Carissa, Rawji, Gulnar, Lynch, Vincent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029211/
https://www.ncbi.nlm.nih.gov/pubmed/24855465
http://dx.doi.org/10.1107/S160053681303256X
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author Hamala, Amanda
Fritz, Carissa
Rawji, Gulnar
Lynch, Vincent
author_facet Hamala, Amanda
Fritz, Carissa
Rawji, Gulnar
Lynch, Vincent
author_sort Hamala, Amanda
collection PubMed
description In the title complex, [PtCl(2)(C(12)H(6)N(2)O(2))]·CH(3)CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N(2)Cl(2) donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any π–π inter­actions between aromatic rings.
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spelling pubmed-40292112014-05-22 An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II) Hamala, Amanda Fritz, Carissa Rawji, Gulnar Lynch, Vincent Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PtCl(2)(C(12)H(6)N(2)O(2))]·CH(3)CN, the Pt(II) atom lies in a slightly distorted square-planar arrangement defined by an N(2)Cl(2) donor set. In the packed structure, columns of complex moieties are stacked such that the neighboring units are oriented at 180° and laterally displaced with respect to each other. This prevents any overlap of the phenanthroline rings and thus there is no possibility of any π–π inter­actions between aromatic rings. International Union of Crystallography 2013-12-11 /pmc/articles/PMC4029211/ /pubmed/24855465 http://dx.doi.org/10.1107/S160053681303256X Text en © Hamala et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hamala, Amanda
Fritz, Carissa
Rawji, Gulnar
Lynch, Vincent
An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title_full An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title_fullStr An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title_full_unstemmed An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title_short An acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(II)
title_sort acetonitrile solvatomorph of di­chlorido­(1,10-phenanthroline-5,6-dione)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029211/
https://www.ncbi.nlm.nih.gov/pubmed/24855465
http://dx.doi.org/10.1107/S160053681303256X
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