N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine

The title mol­ecule, C(24)H(25)NOSi, is a hydrolysis product of the reaction between 9-tri­methyl­silyfluorenyl lithium and 2-meth­oxy­benzo­nitrile. The fluorene ring system is substanti­ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane for...

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Detalles Bibliográficos
Autores principales: Li, Zhong-Yuan, Wang, Peng, Chen, Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029215/
https://www.ncbi.nlm.nih.gov/pubmed/24855469
http://dx.doi.org/10.1107/S1600536813033424
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author Li, Zhong-Yuan
Wang, Peng
Chen, Xia
author_facet Li, Zhong-Yuan
Wang, Peng
Chen, Xia
author_sort Li, Zhong-Yuan
collection PubMed
description The title mol­ecule, C(24)H(25)NOSi, is a hydrolysis product of the reaction between 9-tri­methyl­silyfluorenyl lithium and 2-meth­oxy­benzo­nitrile. The fluorene ring system is substanti­ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth­oxy­benzyl­amine ring plane. In the crystal, mol­ecules are linked by N—H⋯π and C—H⋯π inter­actions, which leads to the formation of two-dimensional network lying parallel to the bc plane.
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spelling pubmed-40292152014-05-22 N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine Li, Zhong-Yuan Wang, Peng Chen, Xia Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(24)H(25)NOSi, is a hydrolysis product of the reaction between 9-tri­methyl­silyfluorenyl lithium and 2-meth­oxy­benzo­nitrile. The fluorene ring system is substanti­ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth­oxy­benzyl­amine ring plane. In the crystal, mol­ecules are linked by N—H⋯π and C—H⋯π inter­actions, which leads to the formation of two-dimensional network lying parallel to the bc plane. International Union of Crystallography 2013-12-14 /pmc/articles/PMC4029215/ /pubmed/24855469 http://dx.doi.org/10.1107/S1600536813033424 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhong-Yuan
Wang, Peng
Chen, Xia
N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title_full N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title_fullStr N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title_full_unstemmed N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title_short N-[(9H-Fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
title_sort n-[(9h-fluoren-9-yl­idene)(2-meth­oxy­phen­yl)meth­yl]-1,1,1-tri­methyl­silanamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029215/
https://www.ncbi.nlm.nih.gov/pubmed/24855469
http://dx.doi.org/10.1107/S1600536813033424
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