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2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide

The title mol­ecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are assembled into inversion dimers...

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Detalles Bibliográficos
Autores principales: de Bittencourt, Viviane Conceição Duarte, Vicenti, Juliano Rosa de Menezes, Velasques, Jecika Maciel, Zambiazi, Priscilla Jussiane, Gervini, Vanessa Carratu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/
https://www.ncbi.nlm.nih.gov/pubmed/24855470
http://dx.doi.org/10.1107/S1600536813033369
Descripción
Sumario:The title mol­ecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl inter­actions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking inter­actions [centroid–centroid distance = 3.849 (2) Å].