Cargando…
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide
The title molecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/ https://www.ncbi.nlm.nih.gov/pubmed/24855470 http://dx.doi.org/10.1107/S1600536813033369 |
_version_ | 1782317174179758080 |
---|---|
author | de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu |
author_facet | de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu |
author_sort | de Bittencourt, Viviane Conceição Duarte |
collection | PubMed |
description | The title molecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl interactions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å]. |
format | Online Article Text |
id | pubmed-4029216 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40292162014-05-22 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl interactions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å]. International Union of Crystallography 2013-12-14 /pmc/articles/PMC4029216/ /pubmed/24855470 http://dx.doi.org/10.1107/S1600536813033369 Text en © Bittencourt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title | 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title_full | 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title_fullStr | 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title_full_unstemmed | 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title_short | 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
title_sort | 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/ https://www.ncbi.nlm.nih.gov/pubmed/24855470 http://dx.doi.org/10.1107/S1600536813033369 |
work_keys_str_mv | AT debittencourtvivianeconceicaoduarte 25chloro2oxoindolin3ylidenehydrazinecarbothioamide AT vicentijulianorosademenezes 25chloro2oxoindolin3ylidenehydrazinecarbothioamide AT velasquesjecikamaciel 25chloro2oxoindolin3ylidenehydrazinecarbothioamide AT zambiazipriscillajussiane 25chloro2oxoindolin3ylidenehydrazinecarbothioamide AT gervinivanessacarratu 25chloro2oxoindolin3ylidenehydrazinecarbothioamide |