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2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide

The title mol­ecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are assembled into inversion dimers...

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Autores principales: de Bittencourt, Viviane Conceição Duarte, Vicenti, Juliano Rosa de Menezes, Velasques, Jecika Maciel, Zambiazi, Priscilla Jussiane, Gervini, Vanessa Carratu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/
https://www.ncbi.nlm.nih.gov/pubmed/24855470
http://dx.doi.org/10.1107/S1600536813033369
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author de Bittencourt, Viviane Conceição Duarte
Vicenti, Juliano Rosa de Menezes
Velasques, Jecika Maciel
Zambiazi, Priscilla Jussiane
Gervini, Vanessa Carratu
author_facet de Bittencourt, Viviane Conceição Duarte
Vicenti, Juliano Rosa de Menezes
Velasques, Jecika Maciel
Zambiazi, Priscilla Jussiane
Gervini, Vanessa Carratu
author_sort de Bittencourt, Viviane Conceição Duarte
collection PubMed
description The title mol­ecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl inter­actions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking inter­actions [centroid–centroid distance = 3.849 (2) Å].
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spelling pubmed-40292162014-05-22 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(9)H(7)ClN(4)OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl inter­actions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking inter­actions [centroid–centroid distance = 3.849 (2) Å]. International Union of Crystallography 2013-12-14 /pmc/articles/PMC4029216/ /pubmed/24855470 http://dx.doi.org/10.1107/S1600536813033369 Text en © Bittencourt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Bittencourt, Viviane Conceição Duarte
Vicenti, Juliano Rosa de Menezes
Velasques, Jecika Maciel
Zambiazi, Priscilla Jussiane
Gervini, Vanessa Carratu
2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_full 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_fullStr 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_short 2-(5-Chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
title_sort 2-(5-chloro-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/
https://www.ncbi.nlm.nih.gov/pubmed/24855470
http://dx.doi.org/10.1107/S1600536813033369
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