Ag-SiO(2)-Er(2)O(3) Nanocomposites: Highly Effective Upconversion Luminescence at High Power Excitation and High Temperature

Rare Earth (RE) activated upconversion phosphors (UCPs), have demonstrated significant application potentials in some front fields, including solar energy conversion and bio-application. However, some bottleneck problems should be overcame, such as the lower upconversion efficiency, narrower excitation band, concentration-quenching and temperature-quenching. To solve these problems, the Ag-SiO(2)-Er(2)O(3) nanocomposites were fabricated, in which the upconversion luminescence (UCL) of Er(2)O(3) was white broadband. Through the interaction of Er(2)O(3) with surface plasmon (SP) of silver nanoparticles (SNPs), the threshold power for generating broadbands was suppressed largely in contrast to the Er(2)O(3) nanoparticles (NPs), while the UCL brightness was enhanced remarkably, ranging from several to 10(4) times, which strongly depended on the power density of excitation light. At excitation power density of 1.50 W/mm(2) of 980 nm light, the UCL intensity of Ag-SiO(2)-Er(2)O(3) is 40-folds than the well-known NaYF(4):Yb(3+),Er(3+) commercial powders. And more, it is also interesting to observe that the composites demonstrate two excitation bands extending of 780–980 nm, highly improved UCL with elevated temperature and excitation power density. The UCL mechanism related to UCL enhancement was carefully studied.