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Hydroxo-Bridged Dicopper(II,III) and -(III,III) Complexes: Models for Putative Intermediates in Oxidation Catalysis

[Image: see text] A macrocyclic ligand (L(4–)) comprising two pyridine(dicarboxamide) donors was used to target reactive copper species relevant to proposed intermediates in catalytic hydrocarbon oxidations by particulate methane monooxygenase and heterogeneous zeolite systems. Treatment of LH(4) wi...

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Detalles Bibliográficos
Autores principales: Halvagar, Mohammad Reza, Solntsev, Pavlo V., Lim, Hyeongtaek, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Cramer, Christopher J., Tolman, William B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4046753/
https://www.ncbi.nlm.nih.gov/pubmed/24821432
http://dx.doi.org/10.1021/ja503629r