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Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene
[Image: see text] In the asymmetric hydrovinylation (HV) of an E/Z-mixture of a prototypical 1,3-diene with (S,S)-(DIOP)CoCl(2) or (S,S)-(BDPP)CoCl(2) catalyst in the presence of Me(3)Al, the (E)-isomer reacts significantly faster, leaving behind the Z-isomer intact at the end of the reaction. The p...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4046774/ https://www.ncbi.nlm.nih.gov/pubmed/24712838 http://dx.doi.org/10.1021/ja501979g |