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Ligand-Enabled γ-C–H Olefination and Carbonylation: Construction of β-Quaternary Carbon Centers

[Image: see text] Monoselective γ-C–H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quatern...

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Detalles Bibliográficos
Autores principales: Li, Suhua, Chen, Gang, Feng, Chen-Guo, Gong, Wei, Yu, Jin-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4049142/
https://www.ncbi.nlm.nih.gov/pubmed/24666182
http://dx.doi.org/10.1021/ja501689j