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3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole

In the title compound, C(26)H(19)BrN(2)O(5)S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitro­phenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenyl­sulfonyl and nitro­phenyl...

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Detalles Bibliográficos
Autores principales: Gopinath, S., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4050995/
https://www.ncbi.nlm.nih.gov/pubmed/24940279
http://dx.doi.org/10.1107/S160053681401143X
Descripción
Sumario:In the title compound, C(26)H(19)BrN(2)O(5)S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitro­phenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenyl­sulfonyl and nitro­phenyl groups, making dihedral angles of 85.43 (15) and 88.62 (12)°, respectively. The mol­ecular conformation is stabilized by two C—H⋯O hydrogen bonds involving the sulfone group, which form similar six-membered rings. In the crystal, mol­ecules symmetrically related by a glide plane are linked in C(6) chains parallel to [001] by C—H⋯O hydrogen bonds formed with the participation of the nitro group. The chains are reinforced by additional C—H⋯π inter­actions.