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3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole

In the title compound, C(26)H(19)BrN(2)O(5)S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitro­phenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenyl­sulfonyl and nitro­phenyl...

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Autores principales: Gopinath, S., Sethusankar, K., Saravanan, Velu, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4050995/
https://www.ncbi.nlm.nih.gov/pubmed/24940279
http://dx.doi.org/10.1107/S160053681401143X
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author Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_facet Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
author_sort Gopinath, S.
collection PubMed
description In the title compound, C(26)H(19)BrN(2)O(5)S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitro­phenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenyl­sulfonyl and nitro­phenyl groups, making dihedral angles of 85.43 (15) and 88.62 (12)°, respectively. The mol­ecular conformation is stabilized by two C—H⋯O hydrogen bonds involving the sulfone group, which form similar six-membered rings. In the crystal, mol­ecules symmetrically related by a glide plane are linked in C(6) chains parallel to [001] by C—H⋯O hydrogen bonds formed with the participation of the nitro group. The chains are reinforced by additional C—H⋯π inter­actions.
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spelling pubmed-40509952014-06-17 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole Gopinath, S. Sethusankar, K. Saravanan, Velu Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(19)BrN(2)O(5)S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitro­phenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenyl­sulfonyl and nitro­phenyl groups, making dihedral angles of 85.43 (15) and 88.62 (12)°, respectively. The mol­ecular conformation is stabilized by two C—H⋯O hydrogen bonds involving the sulfone group, which form similar six-membered rings. In the crystal, mol­ecules symmetrically related by a glide plane are linked in C(6) chains parallel to [001] by C—H⋯O hydrogen bonds formed with the participation of the nitro group. The chains are reinforced by additional C—H⋯π inter­actions. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4050995/ /pubmed/24940279 http://dx.doi.org/10.1107/S160053681401143X Text en © Gopinath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gopinath, S.
Sethusankar, K.
Saravanan, Velu
Mohanakrishnan, Arasambattu K.
3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title_full 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title_fullStr 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title_full_unstemmed 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title_short 3-Bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9H-carbazole
title_sort 3-bromo­methyl-4-meth­oxy-2-(2-nitro­phen­yl)-9-phenyl­sulfonyl-9h-carbazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4050995/
https://www.ncbi.nlm.nih.gov/pubmed/24940279
http://dx.doi.org/10.1107/S160053681401143X
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