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Cs(3)ScCl(6)
Crystals of tricaesium scandium(III) hexachloride were obtained as a side product from the reaction of U, SnCl(2), Sc, and S in a CsCl flux at 1073 K. Cs(3)ScCl(6) crystallizes in the Rb(3)YCl(6) structure type. The asymmetric unit comprises three Cs sites, two Sc sites, and six Cl sites, all of wh...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4050997/ https://www.ncbi.nlm.nih.gov/pubmed/24940185 http://dx.doi.org/10.1107/S1600536814009799 |
| _version_ | 1782320036118003712 |
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| author | Ward, Matthew D. Ibers, James A. |
| author_facet | Ward, Matthew D. Ibers, James A. |
| author_sort | Ward, Matthew D. |
| collection | PubMed |
| description | Crystals of tricaesium scandium(III) hexachloride were obtained as a side product from the reaction of U, SnCl(2), Sc, and S in a CsCl flux at 1073 K. Cs(3)ScCl(6) crystallizes in the Rb(3)YCl(6) structure type. The asymmetric unit comprises three Cs sites, two Sc sites, and six Cl sites, all of which have site symmetry 1, except for the two Sc sites that have site symmetries of 2 and -1, respectively. The structure is composed of isolated [ScCl(6)](3−) octahedra that are surrounded by Cs(+) cations. Two Cs(+) cations have interactions with eight Cl(−) anions, while the third has interactions with ten Cl(−) anions. |
| format | Online Article Text |
| id | pubmed-4050997 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40509972014-06-17 Cs(3)ScCl(6) Ward, Matthew D. Ibers, James A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Crystals of tricaesium scandium(III) hexachloride were obtained as a side product from the reaction of U, SnCl(2), Sc, and S in a CsCl flux at 1073 K. Cs(3)ScCl(6) crystallizes in the Rb(3)YCl(6) structure type. The asymmetric unit comprises three Cs sites, two Sc sites, and six Cl sites, all of which have site symmetry 1, except for the two Sc sites that have site symmetries of 2 and -1, respectively. The structure is composed of isolated [ScCl(6)](3−) octahedra that are surrounded by Cs(+) cations. Two Cs(+) cations have interactions with eight Cl(−) anions, while the third has interactions with ten Cl(−) anions. International Union of Crystallography 2014-05-10 /pmc/articles/PMC4050997/ /pubmed/24940185 http://dx.doi.org/10.1107/S1600536814009799 Text en © Ward and Ibers 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Inorganic Papers Ward, Matthew D. Ibers, James A. Cs(3)ScCl(6) |
| title | Cs(3)ScCl(6)
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| title_full | Cs(3)ScCl(6)
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| title_fullStr | Cs(3)ScCl(6)
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| title_full_unstemmed | Cs(3)ScCl(6)
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| title_short | Cs(3)ScCl(6)
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| title_sort | cs(3)sccl(6) |
| topic | Inorganic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4050997/ https://www.ncbi.nlm.nih.gov/pubmed/24940185 http://dx.doi.org/10.1107/S1600536814009799 |
| work_keys_str_mv | AT wardmatthewd cs3sccl6 AT ibersjamesa cs3sccl6 |