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Ba(4)GaN(3)O

Red transparant platelet-shaped single crystals of tetra­barium gallium trinitride oxide, Ba(4)GaN(3)O, were synthesized by the Na flux method. The crystal structure is isotypic with Sr(4)GaN(3)O, containing isolated triangular [GaN(3)](6−) anionic groups. O(2−) atoms are inserted between the slabs...

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Detalles Bibliográficos
Autores principales: Hashimoto, Takayuki, Yamane, Hisanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051001/
https://www.ncbi.nlm.nih.gov/pubmed/24940188
http://dx.doi.org/10.1107/S1600536814010472
Descripción
Sumario:Red transparant platelet-shaped single crystals of tetra­barium gallium trinitride oxide, Ba(4)GaN(3)O, were synthesized by the Na flux method. The crystal structure is isotypic with Sr(4)GaN(3)O, containing isolated triangular [GaN(3)](6−) anionic groups. O(2−) atoms are inserted between the slabs of [Ba(4)GaN(3)](2+), in which the [GaN(3)](6−) groups are surrounded by Ba(2+) atoms.