Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate

The structure of the title compound, (C(7)H(10)N)(4)[H(2)V(10)O(28)]·2H(2)O, was solved from a non-merohedrally twinned crystal (ratio of twin components ∼0.6:0.4). The asymmetric unit consists of one-half deca­vanadate anion (the other half completed by inversion symmetry), two 2,6-di­methyl­pyridi...

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Detalles Bibliográficos
Autores principales: Rakovský, Erik, Krivosudský, Lukáš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051003/
https://www.ncbi.nlm.nih.gov/pubmed/24940209
http://dx.doi.org/10.1107/S1600536814011118
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author Rakovský, Erik
Krivosudský, Lukáš
author_facet Rakovský, Erik
Krivosudský, Lukáš
author_sort Rakovský, Erik
collection PubMed
description The structure of the title compound, (C(7)H(10)N)(4)[H(2)V(10)O(28)]·2H(2)O, was solved from a non-merohedrally twinned crystal (ratio of twin components ∼0.6:0.4). The asymmetric unit consists of one-half deca­vanadate anion (the other half completed by inversion symmetry), two 2,6-di­methyl­pyridinium cations and one water mol­ecule of crystallization. In the crystal, the components are connected by strong N—H⋯O and O—H⋯O hydrogen bonds, forming a supra­molecular chain along the b-axis direction. There are weak C—H⋯O inter­actions between the chains.
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spelling pubmed-40510032014-06-17 Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate Rakovský, Erik Krivosudský, Lukáš Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(7)H(10)N)(4)[H(2)V(10)O(28)]·2H(2)O, was solved from a non-merohedrally twinned crystal (ratio of twin components ∼0.6:0.4). The asymmetric unit consists of one-half deca­vanadate anion (the other half completed by inversion symmetry), two 2,6-di­methyl­pyridinium cations and one water mol­ecule of crystallization. In the crystal, the components are connected by strong N—H⋯O and O—H⋯O hydrogen bonds, forming a supra­molecular chain along the b-axis direction. There are weak C—H⋯O inter­actions between the chains. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051003/ /pubmed/24940209 http://dx.doi.org/10.1107/S1600536814011118 Text en © Rakovský and Krivosudský 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rakovský, Erik
Krivosudský, Lukáš
Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title_full Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title_fullStr Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title_full_unstemmed Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title_short Tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
title_sort tetrakis(2,6-di­methyl­pyridinium) di­hydrogen deca­vanadate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051003/
https://www.ncbi.nlm.nih.gov/pubmed/24940209
http://dx.doi.org/10.1107/S1600536814011118
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