2,4,6-Tri­nitro­phenyl 3-bromo­benzoate

In the title picryl-substituted ester, C(13)H(6)BrN(3)O(8), the mean plane of the central ester C–O–C(=O)–C fragment (r.m.s. deviation= 0.0186 Å) is rotated by 84.73 (7)° and 19.92 (12)° to the picryl and phenyl rings, respectively. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions, f...

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Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Mosquera, Fabricio, Ellena, Javier, Tenorio, Juan C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051004/
https://www.ncbi.nlm.nih.gov/pubmed/24940266
http://dx.doi.org/10.1107/S1600536814010952
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author Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Ellena, Javier
Tenorio, Juan C.
author_facet Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Ellena, Javier
Tenorio, Juan C.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description In the title picryl-substituted ester, C(13)H(6)BrN(3)O(8), the mean plane of the central ester C–O–C(=O)–C fragment (r.m.s. deviation= 0.0186 Å) is rotated by 84.73 (7)° and 19.92 (12)° to the picryl and phenyl rings, respectively. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions, forming centrosymmetric dimers enclosing R (2) (2)(10) and R (2) (2)(22) ring motifs along [001] and further helical chains of dimers enclosing R (2) (2)(10) ring motifs along [010].
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spelling pubmed-40510042014-06-17 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate Moreno-Fuquen, Rodolfo Mosquera, Fabricio Ellena, Javier Tenorio, Juan C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title picryl-substituted ester, C(13)H(6)BrN(3)O(8), the mean plane of the central ester C–O–C(=O)–C fragment (r.m.s. deviation= 0.0186 Å) is rotated by 84.73 (7)° and 19.92 (12)° to the picryl and phenyl rings, respectively. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions, forming centrosymmetric dimers enclosing R (2) (2)(10) and R (2) (2)(22) ring motifs along [001] and further helical chains of dimers enclosing R (2) (2)(10) ring motifs along [010]. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051004/ /pubmed/24940266 http://dx.doi.org/10.1107/S1600536814010952 Text en © Moreno-Fuquen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Mosquera, Fabricio
Ellena, Javier
Tenorio, Juan C.
2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title_full 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title_fullStr 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title_full_unstemmed 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title_short 2,4,6-Tri­nitro­phenyl 3-bromo­benzoate
title_sort 2,4,6-tri­nitro­phenyl 3-bromo­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051004/
https://www.ncbi.nlm.nih.gov/pubmed/24940266
http://dx.doi.org/10.1107/S1600536814010952
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