1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea

The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloro­propanoyl and 4-bromo­phenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thio­ure...

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Detalles Bibliográficos
Autores principales: Abosadiya, Hamza M., Hasbullah, Siti Aishah, Yamin, Bohari M., Fadzil, Adibatul H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051006/
https://www.ncbi.nlm.nih.gov/pubmed/24940263
http://dx.doi.org/10.1107/S1600536814011209
Descripción
Sumario:The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloro­propanoyl and 4-bromo­phenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thio­urea moiety. Intra­molecular N—H⋯O and C—H⋯S hydrogen bonds occur. In the crystal, mol­ecules are linked into chains along the c-axis direction by N—H⋯S, C—H⋯S and C—H⋯O hydrogen bonds.

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