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1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea
The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloropropanoyl and 4-bromophenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thioure...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051006/ https://www.ncbi.nlm.nih.gov/pubmed/24940263 http://dx.doi.org/10.1107/S1600536814011209 |
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author | Abosadiya, Hamza M. Hasbullah, Siti Aishah Yamin, Bohari M. Fadzil, Adibatul H. |
author_facet | Abosadiya, Hamza M. Hasbullah, Siti Aishah Yamin, Bohari M. Fadzil, Adibatul H. |
author_sort | Abosadiya, Hamza M. |
collection | PubMed |
description | The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloropropanoyl and 4-bromophenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thiourea moiety. Intramolecular N—H⋯O and C—H⋯S hydrogen bonds occur. In the crystal, molecules are linked into chains along the c-axis direction by N—H⋯S, C—H⋯S and C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-4051006 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510062014-06-17 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea Abosadiya, Hamza M. Hasbullah, Siti Aishah Yamin, Bohari M. Fadzil, Adibatul H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloropropanoyl and 4-bromophenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thiourea moiety. Intramolecular N—H⋯O and C—H⋯S hydrogen bonds occur. In the crystal, molecules are linked into chains along the c-axis direction by N—H⋯S, C—H⋯S and C—H⋯O hydrogen bonds. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051006/ /pubmed/24940263 http://dx.doi.org/10.1107/S1600536814011209 Text en © Abosadiya et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Abosadiya, Hamza M. Hasbullah, Siti Aishah Yamin, Bohari M. Fadzil, Adibatul H. 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title | 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title_full | 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title_fullStr | 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title_full_unstemmed | 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title_short | 1-(4-Bromophenyl)-3-(3-chloropropanoyl)thiourea |
title_sort | 1-(4-bromophenyl)-3-(3-chloropropanoyl)thiourea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051006/ https://www.ncbi.nlm.nih.gov/pubmed/24940263 http://dx.doi.org/10.1107/S1600536814011209 |
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