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1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea

The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloro­propanoyl and 4-bromo­phenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thio­ure...

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Autores principales: Abosadiya, Hamza M., Hasbullah, Siti Aishah, Yamin, Bohari M., Fadzil, Adibatul H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051006/
https://www.ncbi.nlm.nih.gov/pubmed/24940263
http://dx.doi.org/10.1107/S1600536814011209
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author Abosadiya, Hamza M.
Hasbullah, Siti Aishah
Yamin, Bohari M.
Fadzil, Adibatul H.
author_facet Abosadiya, Hamza M.
Hasbullah, Siti Aishah
Yamin, Bohari M.
Fadzil, Adibatul H.
author_sort Abosadiya, Hamza M.
collection PubMed
description The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloro­propanoyl and 4-bromo­phenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thio­urea moiety. Intra­molecular N—H⋯O and C—H⋯S hydrogen bonds occur. In the crystal, mol­ecules are linked into chains along the c-axis direction by N—H⋯S, C—H⋯S and C—H⋯O hydrogen bonds.
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spelling pubmed-40510062014-06-17 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea Abosadiya, Hamza M. Hasbullah, Siti Aishah Yamin, Bohari M. Fadzil, Adibatul H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)BrClN(2)OS, adopts a trans–cis conformation with respect to the position of the 3-chloro­propanoyl and 4-bromo­phenyl groups, respectively, against the thiono C=S bond across their C—N bonds. The benzene ring makes a dihedral angle of 9.55 (16)° with the N(2)CS thio­urea moiety. Intra­molecular N—H⋯O and C—H⋯S hydrogen bonds occur. In the crystal, mol­ecules are linked into chains along the c-axis direction by N—H⋯S, C—H⋯S and C—H⋯O hydrogen bonds. International Union of Crystallography 2014-05-21 /pmc/articles/PMC4051006/ /pubmed/24940263 http://dx.doi.org/10.1107/S1600536814011209 Text en © Abosadiya et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abosadiya, Hamza M.
Hasbullah, Siti Aishah
Yamin, Bohari M.
Fadzil, Adibatul H.
1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title_full 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title_fullStr 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title_full_unstemmed 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title_short 1-(4-Bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
title_sort 1-(4-bromo­phen­yl)-3-(3-chloro­propan­oyl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051006/
https://www.ncbi.nlm.nih.gov/pubmed/24940263
http://dx.doi.org/10.1107/S1600536814011209
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