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{Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2) O,O′}bis(triphenylphosphane-κP)copper(I)
In the title complex, [Cu(C(8)H(11)NO(5)PS)(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO(2)P(2) tetrahedron. In the six-membered chelate ring, the Cu,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051010/ https://www.ncbi.nlm.nih.gov/pubmed/24940199 http://dx.doi.org/10.1107/S1600536814010095 |
| _version_ | 1782320039036190720 |
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| author | Moroz, Olesia V. Trush, Viktor A. Sliva, Tatiana Yu. Znovjyak, Kateryna O. Amirkhanov, Vladimir M. |
| author_facet | Moroz, Olesia V. Trush, Viktor A. Sliva, Tatiana Yu. Znovjyak, Kateryna O. Amirkhanov, Vladimir M. |
| author_sort | Moroz, Olesia V. |
| collection | PubMed |
| description | In the title complex, [Cu(C(8)H(11)NO(5)PS)(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO(2)P(2) tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively. |
| format | Online Article Text |
| id | pubmed-4051010 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40510102014-06-17 {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2) O,O′}bis(triphenylphosphane-κP)copper(I) Moroz, Olesia V. Trush, Viktor A. Sliva, Tatiana Yu. Znovjyak, Kateryna O. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(8)H(11)NO(5)PS)(C(18)H(15)P)(2)], the Cu(I) ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO(2)P(2) tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051010/ /pubmed/24940199 http://dx.doi.org/10.1107/S1600536814010095 Text en © Moroz et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Moroz, Olesia V. Trush, Viktor A. Sliva, Tatiana Yu. Znovjyak, Kateryna O. Amirkhanov, Vladimir M. {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2) O,O′}bis(triphenylphosphane-κP)copper(I) |
| title | {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
O,O′}bis(triphenylphosphane-κP)copper(I) |
| title_full | {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
O,O′}bis(triphenylphosphane-κP)copper(I) |
| title_fullStr | {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
O,O′}bis(triphenylphosphane-κP)copper(I) |
| title_full_unstemmed | {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
O,O′}bis(triphenylphosphane-κP)copper(I) |
| title_short | {Dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
O,O′}bis(triphenylphosphane-κP)copper(I) |
| title_sort | {dimethyl [(phenylsulfonyl)amido]phosphato-κ(2)
o,o′}bis(triphenylphosphane-κp)copper(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051010/ https://www.ncbi.nlm.nih.gov/pubmed/24940199 http://dx.doi.org/10.1107/S1600536814010095 |
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