1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea

In the title compound, C(9)H(10)BrClN(2)S, the di­methyl­thio­urea group is twisted from the benzene ring plane by 54.38 (6)°. In the crystal, the amino groups are involved in the formation of N—H⋯S hydrogen bonds, which link the mol­ecules into chains along [010]. Weak C—H⋯Cl inter­actions further...

Descripción completa

Detalles Bibliográficos
Autores principales: El-Hiti, Gamal A., Smith, Keith, Hegazy, Amany S., Alotaibi, Mohammad Hayal, Kariuki, Benson M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051011/
https://www.ncbi.nlm.nih.gov/pubmed/24940276
http://dx.doi.org/10.1107/S1600536814011350
_version_ 1782320039257440256
author El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alotaibi, Mohammad Hayal
Kariuki, Benson M.
author_facet El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alotaibi, Mohammad Hayal
Kariuki, Benson M.
author_sort El-Hiti, Gamal A.
collection PubMed
description In the title compound, C(9)H(10)BrClN(2)S, the di­methyl­thio­urea group is twisted from the benzene ring plane by 54.38 (6)°. In the crystal, the amino groups are involved in the formation of N—H⋯S hydrogen bonds, which link the mol­ecules into chains along [010]. Weak C—H⋯Cl inter­actions further link these chains into layers parallel to the ab plane.
format Online
Article
Text
id pubmed-4051011
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40510112014-06-17 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea El-Hiti, Gamal A. Smith, Keith Hegazy, Amany S. Alotaibi, Mohammad Hayal Kariuki, Benson M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)BrClN(2)S, the di­methyl­thio­urea group is twisted from the benzene ring plane by 54.38 (6)°. In the crystal, the amino groups are involved in the formation of N—H⋯S hydrogen bonds, which link the mol­ecules into chains along [010]. Weak C—H⋯Cl inter­actions further link these chains into layers parallel to the ab plane. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051011/ /pubmed/24940276 http://dx.doi.org/10.1107/S1600536814011350 Text en © El-Hiti et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El-Hiti, Gamal A.
Smith, Keith
Hegazy, Amany S.
Alotaibi, Mohammad Hayal
Kariuki, Benson M.
1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title_full 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title_fullStr 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title_full_unstemmed 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title_short 1-(2-Bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
title_sort 1-(2-bromo-4-chloro­phen­yl)-3,3-di­methyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051011/
https://www.ncbi.nlm.nih.gov/pubmed/24940276
http://dx.doi.org/10.1107/S1600536814011350
work_keys_str_mv AT elhitigamala 12bromo4chlorophenyl33dimethylthiourea
AT smithkeith 12bromo4chlorophenyl33dimethylthiourea
AT hegazyamanys 12bromo4chlorophenyl33dimethylthiourea
AT alotaibimohammadhayal 12bromo4chlorophenyl33dimethylthiourea
AT kariukibensonm 12bromo4chlorophenyl33dimethylthiourea

Ejemplares similares