Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium

The title compound, [Li(2)(C(25)H(23)BN(4)OP)(2)], features a centrosymmetric dimeric complex. The four-memberered Li(2)O(2) ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of two different pyrazole rings. The dihedral angle between two pyraz...

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Detalles Bibliográficos
Autores principales: Müller, Manuela, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051015/
https://www.ncbi.nlm.nih.gov/pubmed/24940216
http://dx.doi.org/10.1107/S1600536814011945
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author Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Müller, Manuela
collection PubMed
description The title compound, [Li(2)(C(25)H(23)BN(4)OP)(2)], features a centrosymmetric dimeric complex. The four-memberered Li(2)O(2) ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of two different pyrazole rings. The dihedral angle between two pyrazole rings bonded to the same B atom is 45.66 (9)°. The B—N—N—Li—N—N metalla ring adopts a boat conformation. The crystal packing is stabilized by van der Waals inter­actions only.
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spelling pubmed-40510152014-06-17 Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium Müller, Manuela Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(2)(C(25)H(23)BN(4)OP)(2)], features a centrosymmetric dimeric complex. The four-memberered Li(2)O(2) ring is exactly planar due to symmetry. The Li atom is four-coordinated by two O atoms and by two N atoms of two different pyrazole rings. The dihedral angle between two pyrazole rings bonded to the same B atom is 45.66 (9)°. The B—N—N—Li—N—N metalla ring adopts a boat conformation. The crystal packing is stabilized by van der Waals inter­actions only. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051015/ /pubmed/24940216 http://dx.doi.org/10.1107/S1600536814011945 Text en © Müller et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title_full Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title_fullStr Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title_full_unstemmed Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title_short Bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1H-pyrazol-1-yl)boranuido}dilithium
title_sort bis{μ-[(di­phenyl­phosphor­yl)meth­yl](phen­yl)bis­(1h-pyrazol-1-yl)boranuido}dilithium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051015/
https://www.ncbi.nlm.nih.gov/pubmed/24940216
http://dx.doi.org/10.1107/S1600536814011945
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