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3-(4-Bromo­phen­yl)cyclo­pent-2-en-1-one

In the title compound, C(11)H(9)BrO, the cyclo­pentenone ring is almost planar with an r.m.s. deviation of 0.0097 Å. The largest inter-ring torsion angles [2.4 (3), 1.3 (3) and 3.53 (2)°] reveal only a very small twist between the rings, and suggest that the two rings are conjugated. The mol­ecule i...

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Detalles Bibliográficos
Autores principales: Shurdha, Endrit, Dees, Kelsey, Miller, Hannah A., Iacono, Scott T., Balaich, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051020/
https://www.ncbi.nlm.nih.gov/pubmed/24940269
http://dx.doi.org/10.1107/S160053681401071X
Descripción
Sumario:In the title compound, C(11)H(9)BrO, the cyclo­pentenone ring is almost planar with an r.m.s. deviation of 0.0097 Å. The largest inter-ring torsion angles [2.4 (3), 1.3 (3) and 3.53 (2)°] reveal only a very small twist between the rings, and suggest that the two rings are conjugated. The mol­ecule is slightly bowed, as shown by the small dihedral angle between the rings [5.3 (1)°]. The crystal packing pattern consists of parallel sheets that stack parallel to the ac plane. Each sheet consists of mol­ecules that pack side-to-side with the same relative orientation of phenyl and cyclo­pentenone rings along the a- and c-axis directions. Slipped side-to-side, face-to-face and edge-to-face inter­actions exist between pairs of sheets with edge-to-edge and edge-to-face O⋯H—C(sp (2)) weak hydrogen-bond contacts. A relatively short edge-to-face contact (2.77 Å) also exists between pairs of sheets.