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Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate

The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide...

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Autores principales: Gutiérrez-Márquez, Ricardo A., Crisóstomo-Lucas, Carmela, Reyes-Martínez, Reyna, Hernández-Ortega, Simón, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051021/
https://www.ncbi.nlm.nih.gov/pubmed/24940194
http://dx.doi.org/10.1107/S1600536814009453
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author Gutiérrez-Márquez, Ricardo A.
Crisóstomo-Lucas, Carmela
Reyes-Martínez, Reyna
Hernández-Ortega, Simón
Morales-Morales, David
author_facet Gutiérrez-Márquez, Ricardo A.
Crisóstomo-Lucas, Carmela
Reyes-Martínez, Reyna
Hernández-Ortega, Simón
Morales-Morales, David
author_sort Gutiérrez-Márquez, Ricardo A.
collection PubMed
description The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water mol­ecules form linear chains along [100] by O—H⋯O and O—H⋯S hydrogen bonds, generating eight- and 12-membered rings. C—H⋯Cl inter­actions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bi­pyridine ligand exhibits π–π stacking inter­actions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3).
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spelling pubmed-40510212014-06-17 Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate Gutiérrez-Márquez, Ricardo A. Crisóstomo-Lucas, Carmela Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water mol­ecules form linear chains along [100] by O—H⋯O and O—H⋯S hydrogen bonds, generating eight- and 12-membered rings. C—H⋯Cl inter­actions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bi­pyridine ligand exhibits π–π stacking inter­actions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3). International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051021/ /pubmed/24940194 http://dx.doi.org/10.1107/S1600536814009453 Text en © Gutiérrez-Márquez et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gutiérrez-Márquez, Ricardo A.
Crisóstomo-Lucas, Carmela
Reyes-Martínez, Reyna
Hernández-Ortega, Simón
Morales-Morales, David
Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title_full Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title_fullStr Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title_full_unstemmed Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title_short Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
title_sort di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ(2) n,n′)palladium(ii) dimethyl sulfoxide monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051021/
https://www.ncbi.nlm.nih.gov/pubmed/24940194
http://dx.doi.org/10.1107/S1600536814009453
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