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Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate
The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051021/ https://www.ncbi.nlm.nih.gov/pubmed/24940194 http://dx.doi.org/10.1107/S1600536814009453 |
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author | Gutiérrez-Márquez, Ricardo A. Crisóstomo-Lucas, Carmela Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David |
author_facet | Gutiérrez-Márquez, Ricardo A. Crisóstomo-Lucas, Carmela Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David |
author_sort | Gutiérrez-Márquez, Ricardo A. |
collection | PubMed |
description | The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H⋯O and O—H⋯S hydrogen bonds, generating eight- and 12-membered rings. C—H⋯Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3). |
format | Online Article Text |
id | pubmed-4051021 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510212014-06-17 Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate Gutiérrez-Márquez, Ricardo A. Crisóstomo-Lucas, Carmela Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(18)H(24)N(2))]·(CH(3))(2)SO·H(2)O, the Pd(II) ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H⋯O and O—H⋯S hydrogen bonds, generating eight- and 12-membered rings. C—H⋯Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3). International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051021/ /pubmed/24940194 http://dx.doi.org/10.1107/S1600536814009453 Text en © Gutiérrez-Márquez et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gutiérrez-Márquez, Ricardo A. Crisóstomo-Lucas, Carmela Reyes-Martínez, Reyna Hernández-Ortega, Simón Morales-Morales, David Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2) N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title_full | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title_fullStr | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title_full_unstemmed | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title_short | Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate |
title_sort | dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ(2)
n,n′)palladium(ii) dimethyl sulfoxide monosolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051021/ https://www.ncbi.nlm.nih.gov/pubmed/24940194 http://dx.doi.org/10.1107/S1600536814009453 |
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