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(2,2′-Bipyridine-κ(2) N,N′)dichloridopalladium(II) 1,4-dioxane hemisolvate
The asymmetric unit of the title compound, [PdCl(2)(C(10)H(8)N(2))]·0.5C(4)H(8)O(2), consists of one Pd(II) complex molecule and a half-molecule of 1,4-dioxane, the complete molecule being generated by inversion symmetry. The Pd(II) atom has an almost square-planar coordination formed by the 2,2′...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051027/ https://www.ncbi.nlm.nih.gov/pubmed/24940204 http://dx.doi.org/10.1107/S1600536814009507 |
Sumario: | The asymmetric unit of the title compound, [PdCl(2)(C(10)H(8)N(2))]·0.5C(4)H(8)O(2), consists of one Pd(II) complex molecule and a half-molecule of 1,4-dioxane, the complete molecule being generated by inversion symmetry. The Pd(II) atom has an almost square-planar coordination formed by the 2,2′-bipyridine ligand and two chloride ligands. Two intramolecular C—H⋯Cl hydrogen bonds occur. In the crystal, the Pd(II) complex and 1,4-dioxane molecules are connected by C—H⋯O hydrogen bonds, forming a layer parallel to (10-1). Within the layer, weak π–π interactions [centroid–centroid distance = 3.817 (4) Å] are observed between the pyridine rings. |
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