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(2,2′-Bi­pyridine-κ(2) N,N′)di­chloridopalladium(II) 1,4-dioxane hemisolvate

The asymmetric unit of the title compound, [PdCl(2)(C(10)H(8)N(2))]·0.5C(4)H(8)O(2), consists of one Pd(II) complex mol­ecule and a half-mol­ecule of 1,4-dioxane, the complete mol­ecule being generated by inversion symmetry. The Pd(II) atom has an almost square-planar coordination formed by the 2,2′...

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Detalles Bibliográficos
Autores principales: Gutiérrez Márquez, Ricardo Alfredo, Crisóstomo-Lucas, Carmela, Morales-Morales, David, Hernández-Ortega, Simón
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051027/
https://www.ncbi.nlm.nih.gov/pubmed/24940204
http://dx.doi.org/10.1107/S1600536814009507
Descripción
Sumario:The asymmetric unit of the title compound, [PdCl(2)(C(10)H(8)N(2))]·0.5C(4)H(8)O(2), consists of one Pd(II) complex mol­ecule and a half-mol­ecule of 1,4-dioxane, the complete mol­ecule being generated by inversion symmetry. The Pd(II) atom has an almost square-planar coordination formed by the 2,2′-bi­pyridine ligand and two chloride ligands. Two intra­molecular C—H⋯Cl hydrogen bonds occur. In the crystal, the Pd(II) complex and 1,4-dioxane mol­ecules are connected by C—H⋯O hydrogen bonds, forming a layer parallel to (10-1). Within the layer, weak π–π inter­actions [centroid–centroid distance = 3.817 (4) Å] are observed between the pyridine rings.