(E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime

The title piperidine derivative, C(26)H(26)N(2)O(3), has an E conformation about the N=C bond. The piperidine ring has a chair conformation and its mean plane is almost perpendicular to the attached phenyl rings, making dihedral angles of 87.47 (9) and 87.34 (8)°. The planes of these two phenyl ring...

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Autores principales: Raghuvarman, B., Sivakumar, R., Gokula Krishnan, K., Thanikachalam, V., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051028/
https://www.ncbi.nlm.nih.gov/pubmed/24940283
http://dx.doi.org/10.1107/S1600536814010526
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author Raghuvarman, B.
Sivakumar, R.
Gokula Krishnan, K.
Thanikachalam, V.
Aravindhan, S.
author_facet Raghuvarman, B.
Sivakumar, R.
Gokula Krishnan, K.
Thanikachalam, V.
Aravindhan, S.
author_sort Raghuvarman, B.
collection PubMed
description The title piperidine derivative, C(26)H(26)N(2)O(3), has an E conformation about the N=C bond. The piperidine ring has a chair conformation and its mean plane is almost perpendicular to the attached phenyl rings, making dihedral angles of 87.47 (9) and 87.34 (8)°. The planes of these two phenyl rings are inclined to one another by 60.38 (9)°. The plane of the terminal phenyl ring is tilted at an angle of 32.79 (9)° to the mean plane of the piperidine ring. The mol­ecular conformation is stabilized by two intra­molecular C—H⋯O contacts. There are no significant inter­molecular inter­actions in the crystal.
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spelling pubmed-40510282014-06-17 (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime Raghuvarman, B. Sivakumar, R. Gokula Krishnan, K. Thanikachalam, V. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title piperidine derivative, C(26)H(26)N(2)O(3), has an E conformation about the N=C bond. The piperidine ring has a chair conformation and its mean plane is almost perpendicular to the attached phenyl rings, making dihedral angles of 87.47 (9) and 87.34 (8)°. The planes of these two phenyl rings are inclined to one another by 60.38 (9)°. The plane of the terminal phenyl ring is tilted at an angle of 32.79 (9)° to the mean plane of the piperidine ring. The mol­ecular conformation is stabilized by two intra­molecular C—H⋯O contacts. There are no significant inter­molecular inter­actions in the crystal. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051028/ /pubmed/24940283 http://dx.doi.org/10.1107/S1600536814010526 Text en © Raghuvarman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raghuvarman, B.
Sivakumar, R.
Gokula Krishnan, K.
Thanikachalam, V.
Aravindhan, S.
(E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title_full (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title_fullStr (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title_full_unstemmed (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title_short (E)-1,3-Dimethyl-2,6-di­phenyl­piperidin-4-one O-(phen­oxy­carbon­yl)oxime
title_sort (e)-1,3-dimethyl-2,6-di­phenyl­piperidin-4-one o-(phen­oxy­carbon­yl)oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051028/
https://www.ncbi.nlm.nih.gov/pubmed/24940283
http://dx.doi.org/10.1107/S1600536814010526
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