Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)

Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY(6)]I(10), which is isostructural with the prototypical [RuY(6)]I(10). In particular, [NiY(6)]I(10) is composed of isolated nickel centered yttrium octa­hedra (site symmetry -1) that are fu...

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Detalles Bibliográficos
Autores principales: Steinberg, Simon, Meyer, Gerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051034/
https://www.ncbi.nlm.nih.gov/pubmed/24940186
http://dx.doi.org/10.1107/S1600536814009775
Descripción
Sumario:Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY(6)]I(10), which is isostructural with the prototypical [RuY(6)]I(10). In particular, [NiY(6)]I(10) is composed of isolated nickel centered yttrium octa­hedra (site symmetry -1) that are further surrounded by iodide ligands to construct a three-dimensional cluster complex framework. Although this compound has been previously detected by powder X-ray diffraction techniques [Payne & Corbett (1990 ▶). Inorg. Chem. 29, 2246–2251], details of the crystal structure for triclinic [NiY(6)]I(10) were not provided.

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