Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)

Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY(6)]I(10), which is isostructural with the prototypical [RuY(6)]I(10). In particular, [NiY(6)]I(10) is composed of isolated nickel centered yttrium octa­hedra (site symmetry -1) that are fu...

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Detalles Bibliográficos
Autores principales: Steinberg, Simon, Meyer, Gerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051034/
https://www.ncbi.nlm.nih.gov/pubmed/24940186
http://dx.doi.org/10.1107/S1600536814009775
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author Steinberg, Simon
Meyer, Gerd
author_facet Steinberg, Simon
Meyer, Gerd
author_sort Steinberg, Simon
collection PubMed
description Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY(6)]I(10), which is isostructural with the prototypical [RuY(6)]I(10). In particular, [NiY(6)]I(10) is composed of isolated nickel centered yttrium octa­hedra (site symmetry -1) that are further surrounded by iodide ligands to construct a three-dimensional cluster complex framework. Although this compound has been previously detected by powder X-ray diffraction techniques [Payne & Corbett (1990 ▶). Inorg. Chem. 29, 2246–2251], details of the crystal structure for triclinic [NiY(6)]I(10) were not provided.
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spelling pubmed-40510342014-06-17 Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10) Steinberg, Simon Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY(6)]I(10), which is isostructural with the prototypical [RuY(6)]I(10). In particular, [NiY(6)]I(10) is composed of isolated nickel centered yttrium octa­hedra (site symmetry -1) that are further surrounded by iodide ligands to construct a three-dimensional cluster complex framework. Although this compound has been previously detected by powder X-ray diffraction techniques [Payne & Corbett (1990 ▶). Inorg. Chem. 29, 2246–2251], details of the crystal structure for triclinic [NiY(6)]I(10) were not provided. International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051034/ /pubmed/24940186 http://dx.doi.org/10.1107/S1600536814009775 Text en © Steinberg and Meyer 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Steinberg, Simon
Meyer, Gerd
Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title_full Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title_fullStr Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title_full_unstemmed Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title_short Nickel hexa­yttrium deca­iodide, [NiY(6)]I(10)
title_sort nickel hexa­yttrium deca­iodide, [niy(6)]i(10)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051034/
https://www.ncbi.nlm.nih.gov/pubmed/24940186
http://dx.doi.org/10.1107/S1600536814009775
work_keys_str_mv AT steinbergsimon nickelhexayttriumdecaiodideniy6i10
AT meyergerd nickelhexayttriumdecaiodideniy6i10

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