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2-[(Z)-1,1-Dioxo-2-(2,4,5-trifluorobenzyl)-3,4-dihydro-2H-1,2-benzothiazin-4-ylidene]acetic acid
In the title compound, C(17)H(12)F(3)NO(4)S, the heterocyclic thiazine ring adopts a half-chair conformation and the dihedral angle between the benzene rings is 43.28 (9)°. The α,β-unsaturated C=C group is inclined at an angle of 21.0 (3)° to the benzene ring of the benzothiazine moiety. In the c...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051037/ https://www.ncbi.nlm.nih.gov/pubmed/24940218 http://dx.doi.org/10.1107/S1600536814008903 |
Sumario: | In the title compound, C(17)H(12)F(3)NO(4)S, the heterocyclic thiazine ring adopts a half-chair conformation and the dihedral angle between the benzene rings is 43.28 (9)°. The α,β-unsaturated C=C group is inclined at an angle of 21.0 (3)° to the benzene ring of the benzothiazine moiety. In the crystal, inversion dimers linked by pairs of carboxylic acid O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Each of the F atoms accepts a C(a)—H⋯F (a = aromatic) hydrogen bond from an adjacent molecule, resulting in (001) sheets. |
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