Cargando…

2-[(Z)-1,1-Dioxo-2-(2,4,5-tri­fluoro­benz­yl)-3,4-di­hydro-2H-1,2-benzo­thia­zin-4-yl­idene]acetic acid

In the title compound, C(17)H(12)F(3)NO(4)S, the heterocyclic thia­zine ring adopts a half-chair conformation and the dihedral angle between the benzene rings is 43.28 (9)°. The α,β-unsaturated C=C group is inclined at an angle of 21.0 (3)° to the benzene ring of the benzo­thia­zine moiety. In the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Parveen, Shagufta, Hussain, Saghir, Zhu, Shaojuan, Hao, Xin, Zhu, Changjin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051037/
https://www.ncbi.nlm.nih.gov/pubmed/24940218
http://dx.doi.org/10.1107/S1600536814008903
Descripción
Sumario:In the title compound, C(17)H(12)F(3)NO(4)S, the heterocyclic thia­zine ring adopts a half-chair conformation and the dihedral angle between the benzene rings is 43.28 (9)°. The α,β-unsaturated C=C group is inclined at an angle of 21.0 (3)° to the benzene ring of the benzo­thia­zine moiety. In the crystal, inversion dimers linked by pairs of carb­oxy­lic acid O—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Each of the F atoms accepts a C(a)—H⋯F (a = aromatic) hydrogen bond from an adjacent mol­ecule, resulting in (001) sheets.