Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate

The title compound, C(28)H(33)N(2)S(2)P, adopts the thione tautomeric form, as supported by the C—S distance [1.6744 (18) Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C—N bond. The terminal chain is disordered over two sets of sites with an occupan...

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Autores principales: Asri, Izuddin, Hamid, Malai Haniti S. A., Mirza, Aminul Huq, Ali, Mohammad Akbar, Karim, Mohammad Rezaul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051045/
https://www.ncbi.nlm.nih.gov/pubmed/24940222
http://dx.doi.org/10.1107/S1600536814008459
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author Asri, Izuddin
Hamid, Malai Haniti S. A.
Mirza, Aminul Huq
Ali, Mohammad Akbar
Karim, Mohammad Rezaul
author_facet Asri, Izuddin
Hamid, Malai Haniti S. A.
Mirza, Aminul Huq
Ali, Mohammad Akbar
Karim, Mohammad Rezaul
author_sort Asri, Izuddin
collection PubMed
description The title compound, C(28)H(33)N(2)S(2)P, adopts the thione tautomeric form, as supported by the C—S distance [1.6744 (18) Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C—N bond. The terminal chain is disordered over two sets of sites with an occupancy ratio of 0.732 (3):0.268 (3). In the crystal, pairs of N—N—H hydrogen bonds between the thione groups link neighbouring mol­ecules into centrosymmetric dimers.
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spelling pubmed-40510452014-06-17 Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate Asri, Izuddin Hamid, Malai Haniti S. A. Mirza, Aminul Huq Ali, Mohammad Akbar Karim, Mohammad Rezaul Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(33)N(2)S(2)P, adopts the thione tautomeric form, as supported by the C—S distance [1.6744 (18) Å]. The Schiff base exhibits an E conformation about the C=N bond but a Z conformation about the C—N bond. The terminal chain is disordered over two sets of sites with an occupancy ratio of 0.732 (3):0.268 (3). In the crystal, pairs of N—N—H hydrogen bonds between the thione groups link neighbouring mol­ecules into centrosymmetric dimers. International Union of Crystallography 2014-05-03 /pmc/articles/PMC4051045/ /pubmed/24940222 http://dx.doi.org/10.1107/S1600536814008459 Text en © Asri et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asri, Izuddin
Hamid, Malai Haniti S. A.
Mirza, Aminul Huq
Ali, Mohammad Akbar
Karim, Mohammad Rezaul
Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title_full Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title_fullStr Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title_full_unstemmed Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title_short Octyl (2E)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
title_sort octyl (2e)-2-[2-(di­phenyl­phosphan­yl)benzyl­idene]hydrazinecarbodi­thio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051045/
https://www.ncbi.nlm.nih.gov/pubmed/24940222
http://dx.doi.org/10.1107/S1600536814008459
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