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Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(sulfamerazinate)
The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by fou...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/ https://www.ncbi.nlm.nih.gov/pubmed/24940207 http://dx.doi.org/10.1107/S160053681401068X |
Sumario: | The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethylenediamine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001). |
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