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Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)

The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by fou...

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Detalles Bibliográficos
Autores principales: Direm, Amani, Falek, Wahiba, Pilet, Guillaume, Benali-Cherif, Nourredine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/
https://www.ncbi.nlm.nih.gov/pubmed/24940207
http://dx.doi.org/10.1107/S160053681401068X
Descripción
Sumario:The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethyl­enedi­amine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001).