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Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(sulfamerazinate)
The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by fou...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/ https://www.ncbi.nlm.nih.gov/pubmed/24940207 http://dx.doi.org/10.1107/S160053681401068X |
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author | Direm, Amani Falek, Wahiba Pilet, Guillaume Benali-Cherif, Nourredine |
author_facet | Direm, Amani Falek, Wahiba Pilet, Guillaume Benali-Cherif, Nourredine |
author_sort | Direm, Amani |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethylenediamine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001). |
format | Online Article Text |
id | pubmed-4051046 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510462014-06-17 Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(sulfamerazinate) Direm, Amani Falek, Wahiba Pilet, Guillaume Benali-Cherif, Nourredine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethylenediamine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001). International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051046/ /pubmed/24940207 http://dx.doi.org/10.1107/S160053681401068X Text en © Direm et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Direm, Amani Falek, Wahiba Pilet, Guillaume Benali-Cherif, Nourredine Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) bis(sulfamerazinate) |
title | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(sulfamerazinate) |
title_full | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(sulfamerazinate) |
title_fullStr | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(sulfamerazinate) |
title_full_unstemmed | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(sulfamerazinate) |
title_short | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) bis(sulfamerazinate) |
title_sort | diaquabis(ethylenediamine-κ(2)
n,n′)copper(ii) bis(sulfamerazinate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/ https://www.ncbi.nlm.nih.gov/pubmed/24940207 http://dx.doi.org/10.1107/S160053681401068X |
work_keys_str_mv | AT diremamani diaquabisethylenediaminek2nncopperiibissulfamerazinate AT falekwahiba diaquabisethylenediaminek2nncopperiibissulfamerazinate AT piletguillaume diaquabisethylenediaminek2nncopperiibissulfamerazinate AT benalicherifnourredine diaquabisethylenediaminek2nncopperiibissulfamerazinate |