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Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)

The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by fou...

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Autores principales: Direm, Amani, Falek, Wahiba, Pilet, Guillaume, Benali-Cherif, Nourredine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/
https://www.ncbi.nlm.nih.gov/pubmed/24940207
http://dx.doi.org/10.1107/S160053681401068X
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author Direm, Amani
Falek, Wahiba
Pilet, Guillaume
Benali-Cherif, Nourredine
author_facet Direm, Amani
Falek, Wahiba
Pilet, Guillaume
Benali-Cherif, Nourredine
author_sort Direm, Amani
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethyl­enedi­amine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001).
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spelling pubmed-40510462014-06-17 Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate) Direm, Amani Falek, Wahiba Pilet, Guillaume Benali-Cherif, Nourredine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(2)H(8)N(2))(2)(H(2)O)(2)](C(11)H(11)N(4)O(2)S)(2), contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethyl­enedi­amine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H⋯N, O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonding into a two-dimensional network parallel to (001). International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051046/ /pubmed/24940207 http://dx.doi.org/10.1107/S160053681401068X Text en © Direm et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Direm, Amani
Falek, Wahiba
Pilet, Guillaume
Benali-Cherif, Nourredine
Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title_full Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title_fullStr Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title_full_unstemmed Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title_short Di­aqua­bis­(ethyl­enedi­amine-κ(2) N,N′)copper(II) bis­(sulfamerazinate)
title_sort di­aqua­bis­(ethyl­enedi­amine-κ(2) n,n′)copper(ii) bis­(sulfamerazinate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051046/
https://www.ncbi.nlm.nih.gov/pubmed/24940207
http://dx.doi.org/10.1107/S160053681401068X
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