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A new polymorph of N-(2-{N′-[(1E)-2-hydroxybenzylidene]hydrazinecarbonyl}phenyl)benzamide
The title compound, C(21)H(17)N(3)O(3), is a new polymorph of an already published structure [Shashidhar et al. (2006 ▶). Acta Cryst. E62, o4473–o4475]. The previously reported structure crystallizes in the monoclinic space group C2/c, whereas the structure reported here is in the tetragonal space...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051047/ https://www.ncbi.nlm.nih.gov/pubmed/24940232 http://dx.doi.org/10.1107/S1600536814010010 |
Sumario: | The title compound, C(21)H(17)N(3)O(3), is a new polymorph of an already published structure [Shashidhar et al. (2006 ▶). Acta Cryst. E62, o4473–o4475]. The previously reported structure crystallizes in the monoclinic space group C2/c, whereas the structure reported here is in the tetragonal space group I4(1)/a. The bond lengths and angles are similar in both structures. The molecule adopts an extended conformation via intramolecular N—H⋯O and O—H⋯N hydrogen bonds; the terminal phenyl ring and the hydroxylphenyl ring are twisted with respect to the central benzene ring by 44.43 (7) and 21.99 (8)°, respectively. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, weak C—H⋯O hydrogen bonds and weak C—H⋯π interactions into a three-dimensional supramolecular network. |
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