Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)

In the title compound, [Co(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion centre and is coordinated by two thio­cyanate anions, two nicotinamide mol­ecules and two water mol­ecules in a distorted N(2)O(2)S(2) octa­hedral geometry. The amide group is twisted by 31....

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Detalles Bibliográficos
Autores principales: Pandey, Deepanjali, Narvi, Shahid S., Chaudhuri, Siddhartha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051052/
https://www.ncbi.nlm.nih.gov/pubmed/24940215
http://dx.doi.org/10.1107/S1600536814011453
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author Pandey, Deepanjali
Narvi, Shahid S.
Chaudhuri, Siddhartha
author_facet Pandey, Deepanjali
Narvi, Shahid S.
Chaudhuri, Siddhartha
author_sort Pandey, Deepanjali
collection PubMed
description In the title compound, [Co(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion centre and is coordinated by two thio­cyanate anions, two nicotinamide mol­ecules and two water mol­ecules in a distorted N(2)O(2)S(2) octa­hedral geometry. The amide group is twisted by 31.30 (16)° with respect to the pyridine ring. In the crystal, mol­ecules are linked by O—H⋯O, O—H⋯S and N—H⋯S hydrogen bonds into a three-dimensional supra­molecular network. Weak π–π stacking is observed between parallel pyridine rings of adjacent mol­ecules, the centroid–centroid distance being 3.8270 (19) Å.
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spelling pubmed-40510522014-06-17 Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II) Pandey, Deepanjali Narvi, Shahid S. Chaudhuri, Siddhartha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Co(II) cation is located on an inversion centre and is coordinated by two thio­cyanate anions, two nicotinamide mol­ecules and two water mol­ecules in a distorted N(2)O(2)S(2) octa­hedral geometry. The amide group is twisted by 31.30 (16)° with respect to the pyridine ring. In the crystal, mol­ecules are linked by O—H⋯O, O—H⋯S and N—H⋯S hydrogen bonds into a three-dimensional supra­molecular network. Weak π–π stacking is observed between parallel pyridine rings of adjacent mol­ecules, the centroid–centroid distance being 3.8270 (19) Å. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051052/ /pubmed/24940215 http://dx.doi.org/10.1107/S1600536814011453 Text en © Pandey et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pandey, Deepanjali
Narvi, Shahid S.
Chaudhuri, Siddhartha
Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title_full Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title_fullStr Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title_full_unstemmed Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title_short Di­aqua­bis­(nicotinamide-κN (1))bis­(thiocyanato-κS)cobalt(II)
title_sort di­aqua­bis­(nicotinamide-κn (1))bis­(thiocyanato-κs)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051052/
https://www.ncbi.nlm.nih.gov/pubmed/24940215
http://dx.doi.org/10.1107/S1600536814011453
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