(N,N′-Di­ethyl­thio­urea-κS)tris­(triphenylphosphane-κP)silver(I) acetate methanol monosolvate

In the mononuclear title complex, [Ag(C(5)H(12)N(2)S)(C(18)H(15)P)(3)](CH(3)COO)·CH(3)OH, the Ag(I) ion is in a distorted tetra­hedral coordination geometry formed by three P atoms from three tri­phenyl­phosphane ligands and one S atom from an N,N′-di­ethyl­thio­urea ligand. In the crystal, the acetate anion is connected to the complex mol­ecule via a pair of N—H⋯O hydrogen bonds [graph-set motif R (2) (2)(8)] and the solvent methanol mol­ecule is connected to the anion via an O—H⋯O hydrogen bond. This aggregate is further connected through a weak C—H⋯O hydrogen bond, forming a chain along [100]. In addition, sixfold phenyl embraces with inter­molecular distances of 6.6463 (13)–6.667 (2) Å are arranged in a chain along [001]. The combination of hydrogen bonding and phen­yl⋯phenyl inter­actions leads to the formation of a two-dimensional network parallel to (010).