Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)

The title compound, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)Cl(4)], contains cyclo­hexyl­ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(−) ligands and two trans-phenyl groups in a distort...

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Autores principales: Sarr, Modou, Merkens, Carina, Diassé-Sarr, Aminata, Diop, Libasse, Englert, Ulli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051057/
https://www.ncbi.nlm.nih.gov/pubmed/24940206
http://dx.doi.org/10.1107/S160053681401109X
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author Sarr, Modou
Merkens, Carina
Diassé-Sarr, Aminata
Diop, Libasse
Englert, Ulli
author_facet Sarr, Modou
Merkens, Carina
Diassé-Sarr, Aminata
Diop, Libasse
Englert, Ulli
author_sort Sarr, Modou
collection PubMed
description The title compound, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)Cl(4)], contains cyclo­hexyl­ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(−) ligands and two trans-phenyl groups in a distorted octa­hedral configuration. The anions are connected with the cations through N—H⋯Cl hydrogen bonds. Every cation is involved in three N—H⋯Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010).
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spelling pubmed-40510572014-06-17 Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV) Sarr, Modou Merkens, Carina Diassé-Sarr, Aminata Diop, Libasse Englert, Ulli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)Cl(4)], contains cyclo­hexyl­ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(−) ligands and two trans-phenyl groups in a distorted octa­hedral configuration. The anions are connected with the cations through N—H⋯Cl hydrogen bonds. Every cation is involved in three N—H⋯Cl bonds to the chloride ligands of three different anions, and each chloride ligand is linked to two cations. This arrangement leads to a layered structure parallel to (010). International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051057/ /pubmed/24940206 http://dx.doi.org/10.1107/S160053681401109X Text en © Sarr et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarr, Modou
Merkens, Carina
Diassé-Sarr, Aminata
Diop, Libasse
Englert, Ulli
Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title_full Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title_fullStr Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title_full_unstemmed Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title_short Bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(IV)
title_sort bis(cyclo­hexyl­ammonium) tetra­chlorido­diphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051057/
https://www.ncbi.nlm.nih.gov/pubmed/24940206
http://dx.doi.org/10.1107/S160053681401109X
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AT dioplibasse biscyclohexylammoniumtetrachloridodiphenylstannateiv
AT englertulli biscyclohexylammoniumtetrachloridodiphenylstannateiv

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