4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate

In the cation of the title salt, C(9)H(13)N(2)O(2) (+)·C(7)H(3)N(2)O(6) (−), the piperazine ring adopts a slightly distorted chair conformation. Twofold rotational disorder is exhibited by the furan ring in a 0.430 (4):0.570 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the ions into chains a...

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Detalles Bibliográficos
Autores principales: Kavitha, Channappa N., Kaur, Manpreet, Jasinski, Jerry P., Butcher, Ray J., Yathirajan, H.S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051063/
https://www.ncbi.nlm.nih.gov/pubmed/24940274
http://dx.doi.org/10.1107/S160053681401126X
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author Kavitha, Channappa N.
Kaur, Manpreet
Jasinski, Jerry P.
Butcher, Ray J.
Yathirajan, H.S.
author_facet Kavitha, Channappa N.
Kaur, Manpreet
Jasinski, Jerry P.
Butcher, Ray J.
Yathirajan, H.S.
author_sort Kavitha, Channappa N.
collection PubMed
description In the cation of the title salt, C(9)H(13)N(2)O(2) (+)·C(7)H(3)N(2)O(6) (−), the piperazine ring adopts a slightly distorted chair conformation. Twofold rotational disorder is exhibited by the furan ring in a 0.430 (4):0.570 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the ions into chains along [010]. Additional weak C—H⋯O inter­actions are observed, leading to a supra­molecular layer parallel to (011).
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spelling pubmed-40510632014-06-17 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate Kavitha, Channappa N. Kaur, Manpreet Jasinski, Jerry P. Butcher, Ray J. Yathirajan, H.S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title salt, C(9)H(13)N(2)O(2) (+)·C(7)H(3)N(2)O(6) (−), the piperazine ring adopts a slightly distorted chair conformation. Twofold rotational disorder is exhibited by the furan ring in a 0.430 (4):0.570 (4) ratio. In the crystal, N—H⋯O hydrogen bonds link the ions into chains along [010]. Additional weak C—H⋯O inter­actions are observed, leading to a supra­molecular layer parallel to (011). International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051063/ /pubmed/24940274 http://dx.doi.org/10.1107/S160053681401126X Text en © Kavitha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, Channappa N.
Kaur, Manpreet
Jasinski, Jerry P.
Butcher, Ray J.
Yathirajan, H.S.
4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title_full 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title_fullStr 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title_full_unstemmed 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title_short 4-(Furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
title_sort 4-(furan-2-carbon­yl)piperazin-1-ium 3,5-di­nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051063/
https://www.ncbi.nlm.nih.gov/pubmed/24940274
http://dx.doi.org/10.1107/S160053681401126X
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