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Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, formi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051065/ https://www.ncbi.nlm.nih.gov/pubmed/24940201 http://dx.doi.org/10.1107/S1600536814010630 |
Sumario: | The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl(3) octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The molecular conformation is stabilized by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. In the crystal, molecules are linked by nonclassical C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking interactions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing. |
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