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Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)

The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenyl­pyridine­keton picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, formi...

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Autores principales: Akkurt, Mehmet, Khandar, Ali Akbar, Tahir, Muhammad Nawaz, Afkhami, Farhad Akbari, Yazdi, Seyed Abolfazl Hosseini
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051065/
https://www.ncbi.nlm.nih.gov/pubmed/24940201
http://dx.doi.org/10.1107/S1600536814010630
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author Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Afkhami, Farhad Akbari
Yazdi, Seyed Abolfazl Hosseini
author_facet Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Afkhami, Farhad Akbari
Yazdi, Seyed Abolfazl Hosseini
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenyl­pyridine­keton picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl(3) octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The mol­ecular conformation is stabilized by intra­molecular N—H⋯N and C—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked by nonclassical C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking inter­actions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing.
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spelling pubmed-40510652014-06-17 Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium) Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Afkhami, Farhad Akbari Yazdi, Seyed Abolfazl Hosseini Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenyl­pyridine­keton picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl(3) octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The mol­ecular conformation is stabilized by intra­molecular N—H⋯N and C—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked by nonclassical C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking inter­actions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051065/ /pubmed/24940201 http://dx.doi.org/10.1107/S1600536814010630 Text en © Akkurt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akkurt, Mehmet
Khandar, Ali Akbar
Tahir, Muhammad Nawaz
Afkhami, Farhad Akbari
Yazdi, Seyed Abolfazl Hosseini
Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title_full Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title_fullStr Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title_full_unstemmed Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title_short Di-μ-chlorido-bis­(chlorido­{N′-[phen­yl(pyridin-2-yl-κN)methyl­idene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
title_sort di-μ-chlorido-bis­(chlorido­{n′-[phen­yl(pyridin-2-yl-κn)methyl­idene]pyridine-2-carbohydrazide-κ(2) n′,o}cadmium)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051065/
https://www.ncbi.nlm.nih.gov/pubmed/24940201
http://dx.doi.org/10.1107/S1600536814010630
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