Cargando…
Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium)
The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, formi...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051065/ https://www.ncbi.nlm.nih.gov/pubmed/24940201 http://dx.doi.org/10.1107/S1600536814010630 |
_version_ | 1782320051471253504 |
---|---|
author | Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Afkhami, Farhad Akbari Yazdi, Seyed Abolfazl Hosseini |
author_facet | Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Afkhami, Farhad Akbari Yazdi, Seyed Abolfazl Hosseini |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl(3) octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The molecular conformation is stabilized by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. In the crystal, molecules are linked by nonclassical C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking interactions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing. |
format | Online Article Text |
id | pubmed-4051065 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510652014-06-17 Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium) Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Afkhami, Farhad Akbari Yazdi, Seyed Abolfazl Hosseini Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)Cl(4)(C(18)H(14)N(4)O)(2)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd(2+) cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl(3) octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The molecular conformation is stabilized by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. In the crystal, molecules are linked by nonclassical C—H⋯O and C—H⋯Cl hydrogen bonds into a three-dimensional network. In addition, π–π stacking interactions [centroid–centroid distances = 3.777 (2) and 3.631 (2) Å] contribute to the stabilization of the crystal packing. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051065/ /pubmed/24940201 http://dx.doi.org/10.1107/S1600536814010630 Text en © Akkurt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Afkhami, Farhad Akbari Yazdi, Seyed Abolfazl Hosseini Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2) N′,O}cadmium) |
title | Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium) |
title_full | Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium) |
title_fullStr | Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium) |
title_full_unstemmed | Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium) |
title_short | Di-μ-chlorido-bis(chlorido{N′-[phenyl(pyridin-2-yl-κN)methylidene]pyridine-2-carbohydrazide-κ(2)
N′,O}cadmium) |
title_sort | di-μ-chlorido-bis(chlorido{n′-[phenyl(pyridin-2-yl-κn)methylidene]pyridine-2-carbohydrazide-κ(2)
n′,o}cadmium) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051065/ https://www.ncbi.nlm.nih.gov/pubmed/24940201 http://dx.doi.org/10.1107/S1600536814010630 |
work_keys_str_mv | AT akkurtmehmet dimchloridobischloridonphenylpyridin2ylknmethylidenepyridine2carbohydrazidek2nocadmium AT khandaraliakbar dimchloridobischloridonphenylpyridin2ylknmethylidenepyridine2carbohydrazidek2nocadmium AT tahirmuhammadnawaz dimchloridobischloridonphenylpyridin2ylknmethylidenepyridine2carbohydrazidek2nocadmium AT afkhamifarhadakbari dimchloridobischloridonphenylpyridin2ylknmethylidenepyridine2carbohydrazidek2nocadmium AT yazdiseyedabolfazlhosseini dimchloridobischloridonphenylpyridin2ylknmethylidenepyridine2carbohydrazidek2nocadmium |