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6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid
The asymmetric unit of the title compound, C(17)H(18)O(3), comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051067/ https://www.ncbi.nlm.nih.gov/pubmed/24940271 http://dx.doi.org/10.1107/S1600536814010642 |
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author | Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Kwong, Huey Chong Quah, Ching Kheng |
author_facet | Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Kwong, Huey Chong Quah, Ching Kheng |
author_sort | Rahman, Md. Lutfor |
collection | PubMed |
description | The asymmetric unit of the title compound, C(17)H(18)O(3), comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H⋯O hydrogen bonds. Adjacent dimers are further interconnected by C—H⋯O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-4051067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510672014-06-17 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Kwong, Huey Chong Quah, Ching Kheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(18)O(3), comprises three independent molecules with similar geometries. In each molecule, the carbonyl group is twisted away from the napthalene ring system, making dihedral angles of 1.0 (2), 1.05 (19)° and 1.5 (2)°. The butene group in all three molecules are disordered over two sets of sites, with a refined occupancy ratio of 0.664 (6):0.336 (6). In the crystal, molecules are oriented with respect to their carbonyl groups, forming head-to-head dimers via O—H⋯O hydrogen bonds. Adjacent dimers are further interconnected by C—H⋯O hydrogen bonds into chains along the a-axis direction. The crystal structure is further stabilized by weak C—H⋯π interactions. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051067/ /pubmed/24940271 http://dx.doi.org/10.1107/S1600536814010642 Text en © Rahman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rahman, Md. Lutfor Srinivasa, H. T. Mohd. Yusoff, Mashitah Kwong, Huey Chong Quah, Ching Kheng 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title_full | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title_fullStr | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title_full_unstemmed | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title_short | 6-(Hex-5-enyloxy)naphthalene-2-carboxylic acid |
title_sort | 6-(hex-5-enyloxy)naphthalene-2-carboxylic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051067/ https://www.ncbi.nlm.nih.gov/pubmed/24940271 http://dx.doi.org/10.1107/S1600536814010642 |
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