(5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one

In the crystal structure of the title compound, C(14)H(12)Cl(3)NO(2), no classical hydrogen-bonding inter­actions are observed. The methyl­ene fragments of the benzyl groups participate in non-classic hydrogen-bond inter­actions with the carbonyl O atoms of neighboring mol­ecules, generating co-oper...

Descripción completa

Detalles Bibliográficos
Autores principales: Fabiani Claro Flores, Alex, Correia Flores, Darlene, Rosa de Menezes Vicenti, Juliano, Pizzuti, Lucas, Teixeira Campos, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051069/
https://www.ncbi.nlm.nih.gov/pubmed/24940220
http://dx.doi.org/10.1107/S160053681400751X
_version_ 1782320052370931712
author Fabiani Claro Flores, Alex
Correia Flores, Darlene
Rosa de Menezes Vicenti, Juliano
Pizzuti, Lucas
Teixeira Campos, Patrick
author_facet Fabiani Claro Flores, Alex
Correia Flores, Darlene
Rosa de Menezes Vicenti, Juliano
Pizzuti, Lucas
Teixeira Campos, Patrick
author_sort Fabiani Claro Flores, Alex
collection PubMed
description In the crystal structure of the title compound, C(14)H(12)Cl(3)NO(2), no classical hydrogen-bonding inter­actions are observed. The methyl­ene fragments of the benzyl groups participate in non-classic hydrogen-bond inter­actions with the carbonyl O atoms of neighboring mol­ecules, generating co-operative centrosymmetric dimers with R (5) (5)(10) ring motifs. The overall mol­ecular arrangement in the unit cell seems to be highly influenced by secondary non-covalent weak C—Cl⋯π [Cl⋯Cg(phenyl ring) = 3.732 (2) Å] and C—O⋯π [O⋯Cg(pyrrolidine ring) = 2.985 (2) Å] contacts.
format Online
Article
Text
id pubmed-4051069
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40510692014-06-17 (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one Fabiani Claro Flores, Alex Correia Flores, Darlene Rosa de Menezes Vicenti, Juliano Pizzuti, Lucas Teixeira Campos, Patrick Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(12)Cl(3)NO(2), no classical hydrogen-bonding inter­actions are observed. The methyl­ene fragments of the benzyl groups participate in non-classic hydrogen-bond inter­actions with the carbonyl O atoms of neighboring mol­ecules, generating co-operative centrosymmetric dimers with R (5) (5)(10) ring motifs. The overall mol­ecular arrangement in the unit cell seems to be highly influenced by secondary non-covalent weak C—Cl⋯π [Cl⋯Cg(phenyl ring) = 3.732 (2) Å] and C—O⋯π [O⋯Cg(pyrrolidine ring) = 2.985 (2) Å] contacts. International Union of Crystallography 2014-05-03 /pmc/articles/PMC4051069/ /pubmed/24940220 http://dx.doi.org/10.1107/S160053681400751X Text en © Fabiani Claro Flores et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fabiani Claro Flores, Alex
Correia Flores, Darlene
Rosa de Menezes Vicenti, Juliano
Pizzuti, Lucas
Teixeira Campos, Patrick
(5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title_full (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title_fullStr (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title_full_unstemmed (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title_short (5E)-1-Benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
title_sort (5e)-1-benzyl-5-(3,3,3-tri­chloro-2-oxo­propyl­idene)pyrrolidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051069/
https://www.ncbi.nlm.nih.gov/pubmed/24940220
http://dx.doi.org/10.1107/S160053681400751X
work_keys_str_mv AT fabianiclarofloresalex 5e1benzyl5333trichloro2oxopropylidenepyrrolidin2one
AT correiafloresdarlene 5e1benzyl5333trichloro2oxopropylidenepyrrolidin2one
AT rosademenezesvicentijuliano 5e1benzyl5333trichloro2oxopropylidenepyrrolidin2one
AT pizzutilucas 5e1benzyl5333trichloro2oxopropylidenepyrrolidin2one
AT teixeiracampospatrick 5e1benzyl5333trichloro2oxopropylidenepyrrolidin2one

Ejemplares similares