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Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2) N,Se}(triphenylphosphane-κP)palladium(II)
The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent molecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(dimethylamino)methyl]benzeneselenolate ligand. The chloride ligand lies tran...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/ https://www.ncbi.nlm.nih.gov/pubmed/24940202 http://dx.doi.org/10.1107/S1600536814010678 |
Sumario: | The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent molecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(dimethylamino)methyl]benzeneselenolate ligand. The chloride ligand lies trans to selenium and the triphenylphosphane ligand is trans to nitrogen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other. |
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