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Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)

The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent mol­ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di­methyl­amino)­meth­yl]benzene­seleno­late ligand. The chloride ligand lies tran...

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Detalles Bibliográficos
Autores principales: Takaluoma, Esther M., Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/
https://www.ncbi.nlm.nih.gov/pubmed/24940202
http://dx.doi.org/10.1107/S1600536814010678
Descripción
Sumario:The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent mol­ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di­methyl­amino)­meth­yl]benzene­seleno­late ligand. The chloride ligand lies trans to selenium and the tri­phenyl­phosphane ligand is trans to nitro­gen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other.