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Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2) N,Se}(triphenylphosphane-κP)palladium(II)
The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent molecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(dimethylamino)methyl]benzeneselenolate ligand. The chloride ligand lies tran...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/ https://www.ncbi.nlm.nih.gov/pubmed/24940202 http://dx.doi.org/10.1107/S1600536814010678 |
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author | Takaluoma, Esther M. Oilunkaniemi, Raija Laitinen, Risto S. |
author_facet | Takaluoma, Esther M. Oilunkaniemi, Raija Laitinen, Risto S. |
author_sort | Takaluoma, Esther M. |
collection | PubMed |
description | The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent molecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(dimethylamino)methyl]benzeneselenolate ligand. The chloride ligand lies trans to selenium and the triphenylphosphane ligand is trans to nitrogen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other. |
format | Online Article Text |
id | pubmed-4051070 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510702014-06-17 Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2) N,Se}(triphenylphosphane-κP)palladium(II) Takaluoma, Esther M. Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent molecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(dimethylamino)methyl]benzeneselenolate ligand. The chloride ligand lies trans to selenium and the triphenylphosphane ligand is trans to nitrogen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051070/ /pubmed/24940202 http://dx.doi.org/10.1107/S1600536814010678 Text en © Takaluoma et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Takaluoma, Esther M. Oilunkaniemi, Raija Laitinen, Risto S. Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2) N,Se}(triphenylphosphane-κP)palladium(II) |
title | Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
N,Se}(triphenylphosphane-κP)palladium(II) |
title_full | Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
N,Se}(triphenylphosphane-κP)palladium(II) |
title_fullStr | Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
N,Se}(triphenylphosphane-κP)palladium(II) |
title_full_unstemmed | Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
N,Se}(triphenylphosphane-κP)palladium(II) |
title_short | Chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
N,Se}(triphenylphosphane-κP)palladium(II) |
title_sort | chlorido{2-[(dimethylamino)methyl]benzeneselenolato-κ(2)
n,se}(triphenylphosphane-κp)palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/ https://www.ncbi.nlm.nih.gov/pubmed/24940202 http://dx.doi.org/10.1107/S1600536814010678 |
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