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Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)

The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent mol­ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di­methyl­amino)­meth­yl]benzene­seleno­late ligand. The chloride ligand lies tran...

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Autores principales: Takaluoma, Esther M., Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/
https://www.ncbi.nlm.nih.gov/pubmed/24940202
http://dx.doi.org/10.1107/S1600536814010678
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author Takaluoma, Esther M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_facet Takaluoma, Esther M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_sort Takaluoma, Esther M.
collection PubMed
description The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent mol­ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di­methyl­amino)­meth­yl]benzene­seleno­late ligand. The chloride ligand lies trans to selenium and the tri­phenyl­phosphane ligand is trans to nitro­gen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other.
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spelling pubmed-40510702014-06-17 Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II) Takaluoma, Esther M. Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PdCl(C(9)H(12)NSe)(C(18)H(15)P)], contains two independent mol­ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di­methyl­amino)­meth­yl]benzene­seleno­late ligand. The chloride ligand lies trans to selenium and the tri­phenyl­phosphane ligand is trans to nitro­gen. The Pd—Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd—P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd—N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd—Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051070/ /pubmed/24940202 http://dx.doi.org/10.1107/S1600536814010678 Text en © Takaluoma et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Takaluoma, Esther M.
Oilunkaniemi, Raija
Laitinen, Risto S.
Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title_full Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title_fullStr Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title_full_unstemmed Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title_short Chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) N,Se}(tri­phenyl­phosphane-κP)palladium(II)
title_sort chlorido­{2-[(di­methyl­amino)­meth­yl]benzene­seleno­lato-κ(2) n,se}(tri­phenyl­phosphane-κp)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051070/
https://www.ncbi.nlm.nih.gov/pubmed/24940202
http://dx.doi.org/10.1107/S1600536814010678
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AT oilunkaniemiraija chlorido2dimethylaminomethylbenzeneselenolatok2nsetriphenylphosphanekppalladiumii
AT laitinenristos chlorido2dimethylaminomethylbenzeneselenolatok2nsetriphenylphosphanekppalladiumii