5-Cyano-1,3-phenyl­ene di­acetate

In the title mol­ecule, C(11)H(9)NO(4), the two acet­oxy groups are twisted from the plane of the benzene ring by 67.89 (4) and 53.30 (5)°. Both carbonyl groups are on the same side of the aromatic ring. In the crystal, weak C—H⋯O hydrogen bonds link mol­ecules into layers parallel to the ac plane....

Descripción completa

Detalles Bibliográficos
Autores principales: Abbassi, Bahar, Brumfield, Michela, Jones, Lloyd M., Nesterov, Vladimir N., Carr, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051073/
https://www.ncbi.nlm.nih.gov/pubmed/24940282
http://dx.doi.org/10.1107/S1600536814011374
_version_ 1782320053285289984
author Abbassi, Bahar
Brumfield, Michela
Jones, Lloyd M.
Nesterov, Vladimir N.
Carr, Andrew J.
author_facet Abbassi, Bahar
Brumfield, Michela
Jones, Lloyd M.
Nesterov, Vladimir N.
Carr, Andrew J.
author_sort Abbassi, Bahar
collection PubMed
description In the title mol­ecule, C(11)H(9)NO(4), the two acet­oxy groups are twisted from the plane of the benzene ring by 67.89 (4) and 53.30 (5)°. Both carbonyl groups are on the same side of the aromatic ring. In the crystal, weak C—H⋯O hydrogen bonds link mol­ecules into layers parallel to the ac plane. The crystal packing exhibits π–π inter­actions between the aromatic rings, indicated by a short inter­centroid distance of 3.767 (3) Å.
format Online
Article
Text
id pubmed-4051073
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-40510732014-06-17 5-Cyano-1,3-phenyl­ene di­acetate Abbassi, Bahar Brumfield, Michela Jones, Lloyd M. Nesterov, Vladimir N. Carr, Andrew J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(11)H(9)NO(4), the two acet­oxy groups are twisted from the plane of the benzene ring by 67.89 (4) and 53.30 (5)°. Both carbonyl groups are on the same side of the aromatic ring. In the crystal, weak C—H⋯O hydrogen bonds link mol­ecules into layers parallel to the ac plane. The crystal packing exhibits π–π inter­actions between the aromatic rings, indicated by a short inter­centroid distance of 3.767 (3) Å. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051073/ /pubmed/24940282 http://dx.doi.org/10.1107/S1600536814011374 Text en © Abbassi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abbassi, Bahar
Brumfield, Michela
Jones, Lloyd M.
Nesterov, Vladimir N.
Carr, Andrew J.
5-Cyano-1,3-phenyl­ene di­acetate
title 5-Cyano-1,3-phenyl­ene di­acetate
title_full 5-Cyano-1,3-phenyl­ene di­acetate
title_fullStr 5-Cyano-1,3-phenyl­ene di­acetate
title_full_unstemmed 5-Cyano-1,3-phenyl­ene di­acetate
title_short 5-Cyano-1,3-phenyl­ene di­acetate
title_sort 5-cyano-1,3-phenyl­ene di­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051073/
https://www.ncbi.nlm.nih.gov/pubmed/24940282
http://dx.doi.org/10.1107/S1600536814011374
work_keys_str_mv AT abbassibahar 5cyano13phenylenediacetate
AT brumfieldmichela 5cyano13phenylenediacetate
AT joneslloydm 5cyano13phenylenediacetate
AT nesterovvladimirn 5cyano13phenylenediacetate
AT carrandrewj 5cyano13phenylenediacetate

Ejemplares similares