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N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide
The title compound, C(12)H(17)N(3)OS, crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the hydrazinecarbothioamide group are 6.9 (4) and 37.2 (5)° in molecules A and B, respectively. An intramolecula...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051077/ https://www.ncbi.nlm.nih.gov/pubmed/24940300 http://dx.doi.org/10.1107/S1600536814012203 |
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author | Anderson, Brian J. Hall, Jeffrey R. Jasinski, Jerry P. |
author_facet | Anderson, Brian J. Hall, Jeffrey R. Jasinski, Jerry P. |
author_sort | Anderson, Brian J. |
collection | PubMed |
description | The title compound, C(12)H(17)N(3)OS, crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the hydrazinecarbothioamide group are 6.9 (4) and 37.2 (5)° in molecules A and B, respectively. An intramolecular O—H⋯N hydrogen bond is observed in each molecule. This serves to maintain an approximately planar conformation for molecule A, but leaves a significant twist between these two groups in molecule B. In the crystal, a weak N—H⋯S interaction is observed, forming inversion dimers among the B molecules and resulting in an R (2) (2)(8) motif. These dimers are further interconnected by weak N—H⋯O and C—H⋯O intermolecular interactions, forming chains along [011]. |
format | Online Article Text |
id | pubmed-4051077 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510772014-06-17 N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide Anderson, Brian J. Hall, Jeffrey R. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(17)N(3)OS, crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angle between the mean planes of the benzene ring and the hydrazinecarbothioamide group are 6.9 (4) and 37.2 (5)° in molecules A and B, respectively. An intramolecular O—H⋯N hydrogen bond is observed in each molecule. This serves to maintain an approximately planar conformation for molecule A, but leaves a significant twist between these two groups in molecule B. In the crystal, a weak N—H⋯S interaction is observed, forming inversion dimers among the B molecules and resulting in an R (2) (2)(8) motif. These dimers are further interconnected by weak N—H⋯O and C—H⋯O intermolecular interactions, forming chains along [011]. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051077/ /pubmed/24940300 http://dx.doi.org/10.1107/S1600536814012203 Text en © Anderson et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Anderson, Brian J. Hall, Jeffrey R. Jasinski, Jerry P. N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title |
N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title_full |
N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title_fullStr |
N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title_full_unstemmed |
N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title_short |
N-Ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
title_sort | n-ethyl-2-[1-(2-hydroxy-4-methylphenyl)ethylidene]hydrazinecarbothioamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051077/ https://www.ncbi.nlm.nih.gov/pubmed/24940300 http://dx.doi.org/10.1107/S1600536814012203 |
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