catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]

In the polymeric title compound, [HgCl(2)(C(20)H(12)N(2))](n), the Hg(II) atom is located on a twofold rotation axis and the benzene ring of the bidentate bridging 1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene (L) ligand is located about a twofold rotation axis. The Hg(II) atom is coordinated by two N a...

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Detalles Bibliográficos
Autores principales: Wang, Bin, Li, Ming, Xie, Ya-bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051079/
https://www.ncbi.nlm.nih.gov/pubmed/24940198
http://dx.doi.org/10.1107/S1600536814010228
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author Wang, Bin
Li, Ming
Xie, Ya-bo
author_facet Wang, Bin
Li, Ming
Xie, Ya-bo
author_sort Wang, Bin
collection PubMed
description In the polymeric title compound, [HgCl(2)(C(20)H(12)N(2))](n), the Hg(II) atom is located on a twofold rotation axis and the benzene ring of the bidentate bridging 1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene (L) ligand is located about a twofold rotation axis. The Hg(II) atom is coordinated by two N atoms of two different L ligands and by two chloride ions in a distorted tetra­hedral geometry. The dihedral angle between the coordinating pyridine and the benzene ring is 12.8 (2)°. The result of the bridging is the formation of a zigzag chain running parallel to [102]. The chains pack with no specific inter­molecular inter­actions between them.
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spelling pubmed-40510792014-06-17 catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′] Wang, Bin Li, Ming Xie, Ya-bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [HgCl(2)(C(20)H(12)N(2))](n), the Hg(II) atom is located on a twofold rotation axis and the benzene ring of the bidentate bridging 1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene (L) ligand is located about a twofold rotation axis. The Hg(II) atom is coordinated by two N atoms of two different L ligands and by two chloride ions in a distorted tetra­hedral geometry. The dihedral angle between the coordinating pyridine and the benzene ring is 12.8 (2)°. The result of the bridging is the formation of a zigzag chain running parallel to [102]. The chains pack with no specific inter­molecular inter­actions between them. International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051079/ /pubmed/24940198 http://dx.doi.org/10.1107/S1600536814010228 Text en © Wang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bin
Li, Ming
Xie, Ya-bo
catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title_full catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title_fullStr catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title_full_unstemmed catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title_short catena-Poly[[di­chlorido­mercury(II)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) N:N′]
title_sort catena-poly[[di­chlorido­mercury(ii)]-μ-1,4-bis­[2-(pyridin-4-yl)ethyn­yl]benzene-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051079/
https://www.ncbi.nlm.nih.gov/pubmed/24940198
http://dx.doi.org/10.1107/S1600536814010228
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