7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one

In the title compound, C(18)H(22)O(4), the cyclo­hexane and cyclo­hexa­none rings adopt normal chair and half-chair conformations, respectively. The dioxolane ring is almost planar, with an r.m.s. deviation of 0.094 (3) Å. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming 2(1...

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Detalles Bibliográficos
Autores principales: Li, Jian, Ma, Jia Qi, Mo, Wei Min, Shen, Zhen Lu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051080/
https://www.ncbi.nlm.nih.gov/pubmed/24940247
http://dx.doi.org/10.1107/S1600536814009040
Descripción
Sumario:In the title compound, C(18)H(22)O(4), the cyclo­hexane and cyclo­hexa­none rings adopt normal chair and half-chair conformations, respectively. The dioxolane ring is almost planar, with an r.m.s. deviation of 0.094 (3) Å. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming 2(1) helical chains along the a-axis direction. The chains are further connected by C—H⋯O hydrogen bonds.

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