7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one

In the title compound, C(18)H(22)O(4), the cyclo­hexane and cyclo­hexa­none rings adopt normal chair and half-chair conformations, respectively. The dioxolane ring is almost planar, with an r.m.s. deviation of 0.094 (3) Å. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming 2(1...

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Detalles Bibliográficos
Autores principales: Li, Jian, Ma, Jia Qi, Mo, Wei Min, Shen, Zhen Lu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051080/
https://www.ncbi.nlm.nih.gov/pubmed/24940247
http://dx.doi.org/10.1107/S1600536814009040
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author Li, Jian
Ma, Jia Qi
Mo, Wei Min
Shen, Zhen Lu
author_facet Li, Jian
Ma, Jia Qi
Mo, Wei Min
Shen, Zhen Lu
author_sort Li, Jian
collection PubMed
description In the title compound, C(18)H(22)O(4), the cyclo­hexane and cyclo­hexa­none rings adopt normal chair and half-chair conformations, respectively. The dioxolane ring is almost planar, with an r.m.s. deviation of 0.094 (3) Å. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming 2(1) helical chains along the a-axis direction. The chains are further connected by C—H⋯O hydrogen bonds.
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spelling pubmed-40510802014-06-17 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one Li, Jian Ma, Jia Qi Mo, Wei Min Shen, Zhen Lu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(22)O(4), the cyclo­hexane and cyclo­hexa­none rings adopt normal chair and half-chair conformations, respectively. The dioxolane ring is almost planar, with an r.m.s. deviation of 0.094 (3) Å. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds, forming 2(1) helical chains along the a-axis direction. The chains are further connected by C—H⋯O hydrogen bonds. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051080/ /pubmed/24940247 http://dx.doi.org/10.1107/S1600536814009040 Text en © Li et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jian
Ma, Jia Qi
Mo, Wei Min
Shen, Zhen Lu
7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title_full 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title_fullStr 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title_full_unstemmed 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title_short 7,7-[Ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
title_sort 7,7-[ethane-1,2-diylbis(oxy)]-2-[hydroxy(phenyl)methyl]bicyclo[3.3.1]nonan-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051080/
https://www.ncbi.nlm.nih.gov/pubmed/24940247
http://dx.doi.org/10.1107/S1600536814009040
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