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1-[Bis(4-fluorophenyl)methyl]-4-[(2Z)-3-phenylprop-2-en-1-yl]piperazine-1,4-diium dichloride hemihydrate
The asymmetric unit of the title monohydrated salt, 2C(26)H(28)F(2)N(2) (2+)·4Cl(−.)H(2)O, consists of a 1-[bis(4-fluorophenyl)methyl]-4-[(2Z)-3-phenylprop-2-en-1-yl]piperazine-1,4-diium cation with a diprotonated piperizine ring in close proximity to two chloride anions and a single water mol...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051083/ https://www.ncbi.nlm.nih.gov/pubmed/24940270 http://dx.doi.org/10.1107/S1600536814011064 |
Sumario: | The asymmetric unit of the title monohydrated salt, 2C(26)H(28)F(2)N(2) (2+)·4Cl(−.)H(2)O, consists of a 1-[bis(4-fluorophenyl)methyl]-4-[(2Z)-3-phenylprop-2-en-1-yl]piperazine-1,4-diium cation with a diprotonated piperizine ring in close proximity to two chloride anions and a single water molecule that lies on a twofold rotation axis. In the cation, the piperazine ring adopts a slightly distorted chair conformation. The dihedral angles between the phenyl ring and the 4-fluorophenyl rings are 89.3 (9) and 35.0 (5)°. The two fluorophenyl rings are inclined at 65.0 (5)° to one another. In the crystal, N—H⋯Cl hydrogen bonds and weak C—H⋯Cl intermolecular interactions link the molecules into chains along [010]. In addition, weak C—H⋯O interactions between the piperizine and prop-2-en-1-yl groups with the water molecule, along with weak C—H⋯Cl interactions between the prop-2en-1-yl and methyl groups with the chloride ions, weak C—H⋯F interactions between the two fluorophenyl groups and weak O—H⋯Cl interactions between the water molecule and chloride ions form a three-dimensional supramolecular network. |
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