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Diethyl 7,7′-dichloro-4-oxo-4H-[1,4′-biquinoline]-3,3′-dicarboxylate
In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, molecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of th...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051084/ https://www.ncbi.nlm.nih.gov/pubmed/24940239 http://dx.doi.org/10.1107/S1600536814010320 |
Sumario: | In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, molecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl⋯N = 3.106 (3) Å]. The molecules also form two kinds of C—H⋯O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further interlinked by the halogen bonds into layers parallel to the bc plane. |
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