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Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate

In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, mol­ecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of th...

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Detalles Bibliográficos
Autores principales: Ishikawa, Yoshinobu, Sugisawa, Yasuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051084/
https://www.ncbi.nlm.nih.gov/pubmed/24940239
http://dx.doi.org/10.1107/S1600536814010320
Descripción
Sumario:In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, mol­ecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl⋯N = 3.106 (3) Å]. The mol­ecules also form two kinds of C—H⋯O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further inter­linked by the halogen bonds into layers parallel to the bc plane.