Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate

In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, mol­ecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of th...

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Detalles Bibliográficos
Autores principales: Ishikawa, Yoshinobu, Sugisawa, Yasuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051084/
https://www.ncbi.nlm.nih.gov/pubmed/24940239
http://dx.doi.org/10.1107/S1600536814010320
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author Ishikawa, Yoshinobu
Sugisawa, Yasuhiro
author_facet Ishikawa, Yoshinobu
Sugisawa, Yasuhiro
author_sort Ishikawa, Yoshinobu
collection PubMed
description In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, mol­ecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl⋯N = 3.106 (3) Å]. The mol­ecules also form two kinds of C—H⋯O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further inter­linked by the halogen bonds into layers parallel to the bc plane.
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spelling pubmed-40510842014-06-17 Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate Ishikawa, Yoshinobu Sugisawa, Yasuhiro Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(18)Cl(2)N(2)O(5), the quinoline and quinolinone moieties are nearly perpendicular to each other, forming a dihedral angle of 82.36 (3)°. In the crystal, mol­ecules form a halogen bond between a Cl atom of a quinolinone moiety and the N atom of the quinoline moiety of the inversion equivalent [Cl⋯N = 3.106 (3) Å]. The mol­ecules also form two kinds of C—H⋯O hydrogen-bonded centrosymmetric inversion dimers, making chains along the c-axis direction which are further inter­linked by the halogen bonds into layers parallel to the bc plane. International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051084/ /pubmed/24940239 http://dx.doi.org/10.1107/S1600536814010320 Text en © Ishikawa and Sugisawa 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishikawa, Yoshinobu
Sugisawa, Yasuhiro
Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title_full Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title_fullStr Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title_full_unstemmed Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title_short Diethyl 7,7′-di­chloro-4-oxo-4H-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
title_sort diethyl 7,7′-di­chloro-4-oxo-4h-[1,4′-bi­quinoline]-3,3′-di­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051084/
https://www.ncbi.nlm.nih.gov/pubmed/24940239
http://dx.doi.org/10.1107/S1600536814010320
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AT sugisawayasuhiro diethyl77dichloro4oxo4h14biquinoline33dicarboxylate

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